{"id":"W2015180412","doi":"10.1002/jms.1686","title":"Generation and dissociation of oxygen‐ and chloride‐bridged iron(III) and manganese(III) tetraphenylporphyrin dimer ions in the gas phase","year":2009,"lang":"en","type":"article","venue":"Journal of Mass Spectrometry","topic":"Hemoglobin structure and function","field":"Biochemistry, Genetics and Molecular Biology","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Chemistry; Dimer; Dissociation (chemistry); Ion; Electrospray ionization; Chloride; Collision-induced dissociation; Mass spectrum; Mass spectrometry; Molecule; Manganese; Oxygen; Inorganic chemistry; Physical chemistry; Tandem mass spectrometry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003702324,0.00009475177,0.0001606027,0.0001271132,0.00005157709,0.00002707015,0.0000534617,0.00009204919,0.000006376949],"category_scores_gemma":[0.00005049651,0.00006902145,0.00004260099,0.0001455942,0.00003989523,0.00001624163,0.00001026282,0.0001409717,6.139752e-8],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000143641,"about_ca_system_score_gemma":0.00001837438,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00000658095,"about_ca_topic_score_gemma":0.000008250421,"domain_scores_codex":[0.9993052,0.00005091687,0.0002690261,0.0001206032,0.000145786,0.0001084466],"domain_scores_gemma":[0.9995959,0.00001775748,0.0002028982,0.00008937485,0.0000488379,0.0000452639],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001574025,0.00005664999,0.00518575,0.000006354457,0.00002717952,0.00000551386,0.0001207478,0.000003748882,0.990541,0.0001615355,0.0002382759,0.003495832],"study_design_scores_gemma":[0.00492336,0.002411888,0.365449,0.00002712355,0.0001490771,0.0005438327,0.0007140627,0.00014982,0.6225373,0.001656839,0.001187757,0.0002499626],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9960391,0.001849576,0.001194112,0.000554279,0.00007973868,0.00008083091,0.000004591766,0.00000126453,0.0001965357],"genre_scores_gemma":[0.9978377,0.001115401,0.0005003553,0.0001239739,0.0003825602,7.208464e-7,0.00001463419,0.000004824844,0.00001980622],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3680037,"threshold_uncertainty_score":0.2814613,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01027558049091383,"score_gpt":0.2585543745747824,"score_spread":0.2482787940838686,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}