{"id":"W2015334462","doi":"10.1021/jp000151o","title":"Potential-Induced Defects in <i>n</i>-Alkanethiol Self-Assembled Monolayers Monitored by Impedance Spectroscopy","year":2000,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":162,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Dielectric spectroscopy; Monolayer; Ionic bonding; Chemistry; Self-assembled monolayer; Ionic liquid; Penetration (warfare); X-ray photoelectron spectroscopy; Ion; Electrical impedance; Chemical physics; Analytical Chemistry (journal); Spectroscopy; Ionic compound; Physical chemistry; Electrochemistry; Nuclear magnetic resonance; Electrode; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001594309,0.0002431996,0.0004124164,0.00001341538,0.0001036545,0.00003779917,0.0006450205,0.0001205495,0.0001766004],"category_scores_gemma":[0.00001941888,0.0001745505,0.0002867446,0.0002969048,0.00002914801,0.00009305153,0.00003037086,0.0008807451,0.00002597598],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00013415,"about_ca_system_score_gemma":0.00008490629,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002240161,"about_ca_topic_score_gemma":5.678908e-7,"domain_scores_codex":[0.9985107,0.00003119178,0.0004724405,0.0002067538,0.0003979131,0.000380984],"domain_scores_gemma":[0.9989652,0.0001287504,0.0003044702,0.0003650884,0.00007211482,0.0001643427],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008344394,0.0004453462,0.00004796547,0.00003546926,0.00008610657,0.000006064434,0.0001114225,0.0002476526,0.9978228,0.000002865756,0.0005693463,0.0005415829],"study_design_scores_gemma":[0.0005965572,0.00003180418,0.00003460769,0.00004303797,0.0001655148,0.00003034576,0.00006849092,0.003096737,0.994758,0.0006123312,0.0003743712,0.0001881777],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9960722,0.0002894565,0.00001807877,0.0003231761,0.00000542735,0.00004030708,0.00000353885,0.0000306275,0.003217192],"genre_scores_gemma":[0.9989235,0.000186914,0.00005715722,0.00005240343,0.0005234378,0.000008517109,0.00000448457,0.00002465094,0.0002189758],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00306471,"threshold_uncertainty_score":0.7117965,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003373212648088882,"score_gpt":0.2290149793358615,"score_spread":0.2256417666877726,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}