{"id":"W2015592243","doi":"10.1002/anie.201206074","title":"Self‐Enhanced Electrochemiluminescence of an Iridium(III) Complex: Mechanistic Insight","year":2012,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Advanced biosensing and bioanalysis techniques","field":"Biochemistry, Genetics and Molecular Biology","cited_by":173,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke; Western University","funders":"","keywords":"Electrochemiluminescence; Iridium; Luminophore; Excited state; Chemistry; Photochemistry; Materials science; Optoelectronics; Luminescence; Physics; Physical chemistry; Catalysis; Atomic physics; Biochemistry; Electrode","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003006574,0.0002510975,0.0001517891,0.0000916976,0.00008888992,0.0003028518,0.0005053648,0.0004420726,0.001294531],"category_scores_gemma":[0.0002058189,0.000127099,0.0002567975,0.00007505156,0.0002236056,0.0004888291,0.0002337823,0.0006948383,0.0003168025],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002835834,"about_ca_system_score_gemma":0.000143189,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001928184,"about_ca_topic_score_gemma":0.0002273078,"domain_scores_codex":[0.999908,0.00001622428,0.000006177099,0.00001830613,0.000027685,0.00002360612],"domain_scores_gemma":[0.9999427,0.00001539932,0.00001261626,0.000008257633,0.00001086878,0.00001021993],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005423078,0.00002920452,0.00004818581,0.00009438239,0.000005760757,0.0001086486,0.00003035172,0.0001560975,0.9968312,0.0005163749,0.0001354665,0.001990136],"study_design_scores_gemma":[0.00001837039,0.00009674808,0.0003175062,0.00000431118,0.00001009978,0.0002572232,0.000008899087,0.00125484,0.9952892,0.0001196597,0.002615586,0.000007596708],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9415521,0.003629904,0.04491905,0.001041505,0.0001051322,0.000101002,0.0002744661,0.0005540007,0.007822791],"genre_scores_gemma":[0.979333,0.001178463,0.01512975,0.0002541063,0.00001883991,0.00004333984,0.0002283937,0.00004266918,0.003771511],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001294531,"threshold_uncertainty_score":0.004330635,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01166634386881139,"score_gpt":0.2770369545611099,"score_spread":0.2653706106922986,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}