{"id":"W2015599350","doi":"10.1016/j.jorganchem.2006.09.004","title":"Synthesis, crystal structure and DFT calculations on 2,6-diisopropylphenylcopper; its use in the preparation of dichloro-2,6-diisopropylphenylphosphine","year":2006,"lang":"en","type":"article","venue":"Journal of Organometallic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Lethbridge","funders":"University of Alberta","keywords":"Chemistry; Crystal structure; Computational chemistry; Combinatorial chemistry; Crystallography","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000401596,0.0003695903,0.0007032304,0.0001432808,0.0001196547,0.0001390339,0.0005281149,0.0002132677,0.007487724],"category_scores_gemma":[0.0006209038,0.0002639252,0.0002909695,0.0005672255,0.00016871,0.0003775427,0.00008110443,0.0004531011,0.000002307745],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00012667,"about_ca_system_score_gemma":0.0001161648,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006511572,"about_ca_topic_score_gemma":0.00003611874,"domain_scores_codex":[0.9973158,0.00004258777,0.001237544,0.0003563931,0.00074594,0.0003017257],"domain_scores_gemma":[0.9976109,0.0004993717,0.0009745471,0.0005702305,0.0002441964,0.0001007762],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001443768,0.0004968079,0.004406543,0.0002691187,0.0001695345,0.0000260823,0.0001920765,0.0003791861,0.9926952,0.0002657131,0.00008533279,0.0008700181],"study_design_scores_gemma":[0.0009215896,0.00006679948,0.02639892,0.0002214839,0.000442259,0.0003623412,0.0004068769,0.0003198863,0.9648057,0.0004993977,0.00510933,0.0004453769],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9969066,0.001037519,0.00002988668,0.0003194483,0.00003395118,0.00009872812,0.0001165885,0.00001527039,0.001441954],"genre_scores_gemma":[0.9984602,0.00009432606,0.0002430201,0.00002421774,0.0003401274,0.000008384175,0.00003834558,0.0000422859,0.0007490339],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02788947,"threshold_uncertainty_score":0.9999813,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01258733168361765,"score_gpt":0.2317098205515178,"score_spread":0.2191224888679001,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}