{"id":"W2015631954","doi":"10.1021/om0102293","title":"Synthesis and Reactivity of a Diruthenium Diazoalkane Complex","year":2001,"lang":"en","type":"article","venue":"Organometallics","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":41,"is_retracted":false,"has_abstract":true,"ca_institutions":"Saint Mary's University; St. Mary's University; Western University","funders":"","keywords":"Chemistry; Phenylacetylene; Ligand (biochemistry); Metallacycle; Alkyne; Formic acid; Medicinal chemistry; Reactivity (psychology); Stereochemistry; Bond cleavage; Metal; Catalysis; X-ray crystallography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001434377,0.0003352919,0.0003888047,0.0002152084,0.0003193198,0.0004416664,0.0005605716,0.0004717231,0.001932803],"category_scores_gemma":[0.0002519233,0.0002548249,0.0001544072,0.0002100416,0.0001716383,0.0001916638,0.0003042418,0.0004949645,0.0006201636],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007483524,"about_ca_system_score_gemma":0.0003080064,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007830756,"about_ca_topic_score_gemma":0.001312669,"domain_scores_codex":[0.9997738,0.00002106608,0.00001387812,0.0000600965,0.00007454968,0.0000566571],"domain_scores_gemma":[0.9999,0.00001211081,0.00001467067,0.00001870307,0.00002037912,0.00003409468],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001058521,0.00006635985,0.0001218755,0.0001354923,0.00002206733,0.0001403698,0.00007723733,0.0006919233,0.9933914,0.001485454,0.0004846091,0.00327736],"study_design_scores_gemma":[0.00007032458,0.0002825243,0.0006277725,0.00000727638,0.00001372247,0.0001714015,0.00001437719,0.001449403,0.9879315,0.0001391351,0.009268006,0.00002447964],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9745582,0.001652619,0.007406326,0.0002353132,0.0001180056,0.0001589103,0.0004940438,0.0003346258,0.01504195],"genre_scores_gemma":[0.9904418,0.0004517581,0.004227392,0.00004840967,0.00001240376,0.00004931939,0.0003167211,0.00004591508,0.004406266],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001932803,"threshold_uncertainty_score":0.006465852,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02259146330395358,"score_gpt":0.2350373115517032,"score_spread":0.2124458482477496,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}