{"id":"W2015653116","doi":"10.1021/om990845n","title":"Reactions of the Binuclear Complexes [MIr(CO)<sub>3</sub>(Ph<sub>2</sub>PCH<sub>2</sub>PPh<sub>2</sub>)<sub>2</sub>] (M = Rh, Ir) with Alkyl Halides:  Dramatic Reactivity Differences as a Function of Metal Combination and Alkyl Halide","year":2000,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Centre National de la Recherche Scientifique","keywords":"Chemistry; Trifluoromethanesulfonate; Iodide; Iridium; Alkyl; Medicinal chemistry; Methylene; Methyl iodide; Yield (engineering); Oxidative addition; Halide; Ligand (biochemistry); Metal; Rhodium; Stereochemistry; Organometallic chemistry; Catalysis; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","insufficient_payload"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.001684447,0.002418975,0.003627272,0.001204033,0.001569108,0.000707792,0.001852735,0.001144332,0.001280301],"category_scores_gemma":[0.0008838265,0.002132997,0.001599124,0.003917224,0.002169515,0.001881429,0.0007240489,0.001810966,0.0004132987],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007825608,"about_ca_system_score_gemma":0.0006682719,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002725379,"about_ca_topic_score_gemma":0.0009213224,"domain_scores_codex":[0.9877053,0.0008968582,0.00346004,0.002860047,0.003091732,0.001985983],"domain_scores_gemma":[0.9897062,0.001630062,0.00325189,0.003588365,0.0009193417,0.0009041031],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005542648,0.002650511,0.001651462,0.001076874,0.002552628,0.00003175401,0.0009765533,0.00008261207,0.9288109,0.0007380924,0.0001924635,0.0606819],"study_design_scores_gemma":[0.002673978,0.0006032844,0.02942294,0.0006960112,0.003678766,0.0002816757,0.001552916,0.000549395,0.954857,0.002181863,0.001305768,0.002196382],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9927482,0.0008394971,0.0003056073,0.0006340855,0.0003721408,0.001468833,0.0007225838,0.0005731655,0.00233586],"genre_scores_gemma":[0.9945542,0.002941436,0.0001335295,0.0001841971,0.0003516346,0.0003082127,0.0007814157,0.0005565512,0.0001887836],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05848552,"threshold_uncertainty_score":0.9997307,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01184446690739196,"score_gpt":0.2040906677540405,"score_spread":0.1922462008466486,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}