{"id":"W2015703751","doi":"10.1021/ic010448g","title":"Pyrazolyl-Bridged Iridium Dimers. 18.<sup>1</sup> Influence of Metal−Metal Bonding on the Geometry of Diiridium(II) Adducts and Hydrido-diiridium Complexes Formed from the Diiridium(I) Prototype [Ir(μ-pz)(PPh<sub>3</sub>)(CO)]<sub>2</sub> (pzH = Pyrazole) by Dihydrogen Addition or Protonation","year":2002,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"","keywords":"Chemistry; Hydride; Adduct; Iridium; Protonation; Crystallography; Metal; Stereochemistry; Crystal structure; Medicinal chemistry; Octahedron; Pyrazole; Catalysis; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0007637565,0.001240218,0.001505101,0.0001781415,0.0008710751,0.0001847994,0.001688014,0.0005855644,0.006539628],"category_scores_gemma":[0.001323135,0.0009173028,0.000612877,0.001368452,0.001202407,0.0005962373,0.0007428516,0.001128139,0.00009675837],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003837885,"about_ca_system_score_gemma":0.0002344582,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008444194,"about_ca_topic_score_gemma":0.0000148058,"domain_scores_codex":[0.9934954,0.0001384708,0.001933298,0.001571957,0.001760454,0.001100439],"domain_scores_gemma":[0.9940323,0.00144091,0.001642704,0.002123089,0.0004000192,0.0003609287],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003295428,0.0007812003,0.0004025376,0.000632641,0.0009899412,0.00001063218,0.0008219866,0.00005328271,0.9888993,0.000024644,0.004504045,0.002550248],"study_design_scores_gemma":[0.001457966,0.0001436644,0.0007891452,0.0003810627,0.000732019,0.00006098884,0.0006850731,0.000665402,0.9898363,0.0001592902,0.004074527,0.001014541],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9922888,0.001338384,0.00001214375,0.001018534,0.00005625509,0.00167629,0.002361867,0.0002231737,0.001024538],"genre_scores_gemma":[0.9964254,0.0004255758,0.00002226841,0.0001823543,0.0004728676,0.000781417,0.001144051,0.0002194512,0.0003266436],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00644287,"threshold_uncertainty_score":0.9993278,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01641180169755639,"score_gpt":0.2112762908691702,"score_spread":0.1948644891716138,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}