{"id":"W2016095454","doi":"10.1002/chin.201410252","title":"ChemInform Abstract: Transition‐Metal‐Catalyzed Allylic Substitution Reactions: Stereoselective Construction of α‐ and β‐Substituted Carbonyl Compounds","year":2014,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Stereoselectivity; Allylic rearrangement; Substitution reaction; Transition metal; Substitution (logic); Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002650511,0.0002882343,0.0004708588,0.0002045432,0.0001573314,0.0000444965,0.000177258,0.0002668402,0.0002848652],"category_scores_gemma":[0.0002210686,0.0002869211,0.0001767631,0.0004687136,0.000376043,0.0005086494,0.00003300074,0.0002229324,0.00001359386],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001674069,"about_ca_system_score_gemma":0.00007629801,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000144815,"about_ca_topic_score_gemma":0.00001219295,"domain_scores_codex":[0.9983602,2.314505e-7,0.0006922442,0.0003161857,0.000345455,0.0002856752],"domain_scores_gemma":[0.9985868,0.0001889675,0.0004622395,0.0004071626,0.0002126247,0.0001421814],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001284864,0.0001214548,0.0001272285,0.0005638652,0.0003338123,0.00000124742,0.0007817679,0.000001466038,0.09779274,0.002005645,0.0001863599,0.897956],"study_design_scores_gemma":[0.0009060228,0.00001196514,0.0009864018,0.0001081175,0.0002314861,0.00009043702,0.0008894202,0.0002057071,0.9891114,0.0002257364,0.006886496,0.0003467895],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.217716,0.0001788488,0.00002554756,0.00004061265,0.00007131797,0.0001052203,0.00005845075,0.0001207975,0.7816833],"genre_scores_gemma":[0.9983131,0.0001287852,0.000168716,0.00001603322,0.0001235376,0.00003739107,0.0003670689,0.00002001054,0.0008253414],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.8976091,"threshold_uncertainty_score":0.9999583,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01066849237787846,"score_gpt":0.2152066086029438,"score_spread":0.2045381162250654,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}