{"id":"W2016224368","doi":"10.1021/ma2003954","title":"“Arm-First” Synthesis of Core-Cross-Linked Multiarm Star Polyethylenes by Coupling Palladium-Catalyzed Ethylene “Living” Polymerization with Atom-Transfer Radical Polymerization","year":2011,"lang":"en","type":"article","venue":"Macromolecules","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":56,"is_retracted":false,"has_abstract":true,"ca_institutions":"Laurentian University","funders":"","keywords":"Polymer chemistry; Atom-transfer radical-polymerization; Catalysis; Palladium; Polymerization; Living free-radical polymerization; Living polymerization; Chemistry; Chain transfer; Ethylene; Radical polymerization; Coupling (piping); Core (optical fiber); Atom (system on chip); Reversible addition−fragmentation chain-transfer polymerization; Photochemistry; Materials science; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001452376,0.0006025159,0.0006703508,0.0001500302,0.0003033546,0.00007779187,0.000489258,0.0003792411,0.001518182],"category_scores_gemma":[0.00009992802,0.0005694412,0.0001755145,0.0003848724,0.0005387368,0.0003748546,0.00008240759,0.000226703,0.00001269187],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006562587,"about_ca_system_score_gemma":0.00009069739,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004082579,"about_ca_topic_score_gemma":0.00003091108,"domain_scores_codex":[0.9970405,0.00004388371,0.0008983751,0.0007908552,0.0005939996,0.0006323676],"domain_scores_gemma":[0.9982085,0.0002988645,0.0004162764,0.0006628818,0.000167458,0.0002460832],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000403243,0.0005088162,0.02355604,0.0002792351,0.000198997,0.00001372088,0.001127071,0.00002331932,0.970455,0.0005031015,0.000002871081,0.00292857],"study_design_scores_gemma":[0.0007226521,0.00006102477,0.003996937,0.00043268,0.0001854639,0.00001599527,0.0002757425,0.001250249,0.9921558,0.00001394141,0.0002132059,0.0006762508],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9486127,0.001185092,0.04854389,0.00004908916,0.00009875043,0.0001983863,0.0004654563,0.0002374253,0.0006091757],"genre_scores_gemma":[0.9966156,0.0004229985,0.001851286,0.00005445318,0.00009793103,0.0001000619,0.0005351547,0.0001858765,0.0001366595],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04800284,"threshold_uncertainty_score":0.9996757,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01414234356766238,"score_gpt":0.2283806406440419,"score_spread":0.2142382970763795,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}