{"id":"W2016240603","doi":"10.1039/c4ay01442a","title":"Simultaneous determination of berberine and palmatine in human plasma and in urine by capillary electrophoresis combined with polypropylene hollow fiber liquid–liquid–liquid microextraction","year":2014,"lang":"en","type":"article","venue":"Analytical Methods","topic":"Microfluidic and Capillary Electrophoresis Applications","field":"Engineering","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"The Society of Obstetricians and Gynaecologists of Canada","funders":"Shantou University","keywords":"Chromatography; Capillary electrophoresis; Palmatine; Chemistry; Capillary action; Fiber; Polypropylene; Berberine; Urine; Analytical Chemistry (journal); High-performance liquid chromatography; Materials science; Composite material; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0005219628,0.0002747939,0.0005286432,0.000264071,0.0000537538,0.00001833283,0.0001036614,0.0001707481,0.00005532791],"category_scores_gemma":[0.0001244432,0.0002560315,0.00003863768,0.0004669249,0.0001294385,0.00008271827,0.00003858726,0.0002799122,0.000001436888],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007756988,"about_ca_system_score_gemma":0.00001498294,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000842927,"about_ca_topic_score_gemma":0.000055838,"domain_scores_codex":[0.9983554,0.0002179292,0.0005544747,0.0003615464,0.0001513328,0.0003592622],"domain_scores_gemma":[0.9989988,0.0004773351,0.00008522571,0.0002574708,0.00005652508,0.0001246331],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001158547,0.0001332753,0.00006197917,0.0001239457,0.0000341246,0.000007866684,0.00005727944,0.00008128144,0.9913177,0.0002087889,0.0001273562,0.006687878],"study_design_scores_gemma":[0.002193494,0.003554091,0.0004082959,0.00007368583,0.0001050363,0.00005205957,0.00002406756,0.05819539,0.9317277,0.00007870519,0.0031819,0.0004055547],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9822007,0.00334333,0.01372909,0.0001340832,0.00001018724,0.0002921689,0.000007069375,0.00004870781,0.0002346686],"genre_scores_gemma":[0.9853791,0.006048682,0.008275005,0.0000278827,0.00002399515,0.00004634714,0.00003933023,0.00005051275,0.0001091239],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05958996,"threshold_uncertainty_score":0.9999892,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00554263795375874,"score_gpt":0.2598799157911185,"score_spread":0.2543372778373598,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}