{"id":"W2016419769","doi":"10.1021/ic700738w","title":"Probing Lead(II) Bonding Environments in 4-Substituted Pyridine Adducts of (2,6-Me<sub>2</sub>C<sub>6</sub>H<sub>3</sub>S)<sub>2</sub>Pb:  An X-ray Structural and Solid-State <sup>207</sup>Pb NMR Study","year":2007,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Crystallography and molecular interactions","field":"Chemistry","cited_by":46,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor; University of Saskatchewan; Mount Allison University","funders":"","keywords":"Chemistry; Pyridine; Adduct; Crystallography; Trigonal bipyramidal molecular geometry; Density functional theory; Chemical shift; Valence (chemistry); Stereochemistry; Computational chemistry; Crystal structure; Physical chemistry; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006905799,0.0002341952,0.0002032722,0.00008286062,0.0001612022,0.0001653263,0.0003276015,0.0002283982,0.001762679],"category_scores_gemma":[0.0001631841,0.0001836434,0.00007828724,0.0001307764,0.0002479214,0.0001436778,0.0002335205,0.0003151207,0.0002680161],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002394829,"about_ca_system_score_gemma":0.0001634865,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001066205,"about_ca_topic_score_gemma":0.001635987,"domain_scores_codex":[0.9999388,0.0000124563,0.00000209648,0.00001302425,0.0000205964,0.00001291417],"domain_scores_gemma":[0.9999447,0.000009896335,0.0000182991,0.000006748727,0.00001089505,0.00000941653],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001455388,0.000008871498,0.0003597567,0.00005605783,0.000007774332,0.00006770763,0.00008693161,0.000275462,0.9976984,0.00009176188,0.00006383216,0.001138043],"study_design_scores_gemma":[0.000009552227,0.0001221538,0.001744375,0.000002490631,0.000007204674,0.0001058257,0.00005291413,0.0005986429,0.9963206,0.0000373164,0.0009930264,0.000005962896],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9971975,0.000376816,0.001220703,0.00003703693,0.000005734108,0.000006619491,0.00008540339,0.00004738921,0.001022799],"genre_scores_gemma":[0.9972872,0.0002491094,0.00124699,0.00002437783,0.000002919113,0.000009476742,0.0001132352,0.00001427332,0.001052456],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001762679,"threshold_uncertainty_score":0.005896807,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008041470232278044,"score_gpt":0.2307029182803803,"score_spread":0.2226614480481022,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}