{"id":"W2016505580","doi":"10.1039/c4py00862f","title":"Synthesis and migration insertion polymerization (MIP) of CpFe(CO)<sub>2</sub>(CH<sub>2</sub>)<sub>6</sub>PPh<sub>2</sub>(FpC6P) for PFpC6P: macromolecule stability, degradability and redox activity","year":2014,"lang":"en","type":"article","venue":"Polymer Chemistry","topic":"biodegradable polymer synthesis and properties","field":"Materials Science","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"Natural Sciences and Engineering Research Council of Canada; China Scholarship Council; University of Waterloo","keywords":"Polymerization; Chemistry; Monomer; Polymer; Redox; Alkyl; Dissociation (chemistry); Polymer chemistry; Phosphine; Macromolecule; Inorganic chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.001826593,0.00124369,0.001506976,0.0002100111,0.0009087968,0.0004493503,0.0006646603,0.0009426541,0.00004197278],"category_scores_gemma":[0.001145656,0.001201485,0.0004406522,0.0005728605,0.001314634,0.001094721,0.0003971825,0.0004908724,0.00002239937],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002670318,"about_ca_system_score_gemma":0.0003617017,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004469187,"about_ca_topic_score_gemma":0.0003545422,"domain_scores_codex":[0.99296,0.0007337187,0.001593239,0.002239497,0.00109034,0.001383247],"domain_scores_gemma":[0.9951813,0.001015833,0.001172576,0.001630728,0.0003623798,0.0006372322],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008698112,0.0005297248,0.002112321,0.00151578,0.0001040859,0.000002538562,0.0004404915,0.000001742208,0.8900713,0.00001979411,0.00009523809,0.1042372],"study_design_scores_gemma":[0.0009677444,0.0002190778,0.003000316,0.000330291,0.0003866356,0.00004994127,0.0002139963,0.001156489,0.9920833,0.0002269242,0.00004676341,0.001318556],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9892495,0.005154073,0.00204482,0.0009839319,0.000369737,0.0009418157,0.0007979705,0.0003155683,0.0001425778],"genre_scores_gemma":[0.9975072,0.0009031062,0.0001869875,0.0001558565,0.0003514442,0.0005204466,0.0001780032,0.0001850554,0.00001190137],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1029186,"threshold_uncertainty_score":0.9990435,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01394278114201149,"score_gpt":0.2140174195549702,"score_spread":0.2000746384129587,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}