{"id":"W2016567384","doi":"10.1002/chin.200024232","title":"ChemInform Abstract: A New Short Synthetic Approach to Chlorocyclopentenones Related to Cryptosporiopsin via a Ring Expansion Strategy: First Synthesis of a Fungitoxic Metabolite from Sporormia affinis.","year":2000,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick","funders":"","keywords":"Chemistry; Ring (chemistry); Metabolite; Service (business); Combinatorial chemistry; Organic chemistry; Biochemistry; Business","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001516329,0.0008406582,0.0003243468,0.0003034099,0.0002851762,0.0003143529,0.0004515001,0.0003785486,0.005789107],"category_scores_gemma":[0.0001260634,0.0001870126,0.0003118972,0.0003687009,0.000227393,0.0005740892,0.0004700025,0.0008117182,0.002801204],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003280337,"about_ca_system_score_gemma":0.0008289291,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005883244,"about_ca_topic_score_gemma":0.00118228,"domain_scores_codex":[0.9999068,0.00001093162,0.000008729923,0.00002036224,0.00002325605,0.00002992516],"domain_scores_gemma":[0.9999413,0.000006125867,0.00001022379,0.000006842715,0.000008231015,0.00002719642],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004588873,0.0002648581,0.0001500234,0.0009709456,0.00004744485,0.001138846,0.0001158556,0.001387922,0.9084787,0.00357492,0.006894359,0.07651731],"study_design_scores_gemma":[0.0001826336,0.00227742,0.001107907,0.00005026358,0.00005328034,0.001218663,0.00005437386,0.001032043,0.8949147,0.001287341,0.09776874,0.00005273052],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5851322,0.03750843,0.2310434,0.003976596,0.004884742,0.002279823,0.01014266,0.0036939,0.1213381],"genre_scores_gemma":[0.8360795,0.02905553,0.06956828,0.001085769,0.0004632885,0.0003657888,0.004650719,0.0003051934,0.05842593],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005789107,"threshold_uncertainty_score":0.01936644,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0165245404787853,"score_gpt":0.247000348770995,"score_spread":0.2304758082922097,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}