{"id":"W2016595467","doi":"10.1021/bc700195y","title":"Synthesis of <i>p</i>-(Di-<i>tert</i>-butyl[<sup>18</sup>F]fluorosilyl)benzaldehyde ([<sup>18</sup>F]SiFA-A) with High Specific Activity by Isotopic Exchange: A Convenient Labeling Synthon for the <sup>18</sup>F-Labeling of N-amino-oxy Derivatized Peptides","year":2007,"lang":"en","type":"article","venue":"Bioconjugate Chemistry","topic":"Radiopharmaceutical Chemistry and Applications","field":"Medicine","cited_by":107,"is_retracted":false,"has_abstract":true,"ca_institutions":"Jewish General Hospital","funders":"","keywords":"Chemistry; Synthon; High-performance liquid chromatography; Biodistribution; Radiochemistry; Stereochemistry; Chromatography; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.001401597,0.001197606,0.001837483,0.0001259887,0.0005560157,0.0001061842,0.00102447,0.000780608,0.001026527],"category_scores_gemma":[0.0006751249,0.0009845025,0.0006257759,0.0008381316,0.001183622,0.0002470916,0.0002683168,0.001061952,0.00001884623],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004166738,"about_ca_system_score_gemma":0.0003370658,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001361806,"about_ca_topic_score_gemma":0.000002057974,"domain_scores_codex":[0.9938074,0.000113028,0.001784331,0.001628912,0.001117675,0.001548621],"domain_scores_gemma":[0.992923,0.002761881,0.0009539964,0.001939692,0.0006649477,0.0007564924],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002182845,0.001144359,0.001074539,0.004222188,0.0006162015,0.00003099103,0.0005281986,0.0008201764,0.9820266,0.00003880201,0.003570486,0.003744566],"study_design_scores_gemma":[0.004968813,0.0001946806,0.0001321754,0.001137749,0.001084881,0.0001221136,0.001461743,0.006137294,0.9676386,0.00005886307,0.01611123,0.0009518645],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9866202,0.002902626,0.002861558,0.001487268,0.00005225679,0.002954237,0.001075648,0.0002613389,0.001784839],"genre_scores_gemma":[0.990074,0.001266945,0.004457466,0.0004158336,0.0008435355,0.001151978,0.0002855705,0.0002171769,0.001287437],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01438805,"threshold_uncertainty_score":0.9998867,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03338413170743306,"score_gpt":0.288825838889908,"score_spread":0.2554417071824749,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}