{"id":"W2016755677","doi":"10.1021/ja062509l","title":"Catalytic Intermolecular Direct Arylation of Perfluorobenzenes","year":2006,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":843,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Catalysis; Reactivity (psychology); Reagent; Palladium; Electrophile; Intermolecular force; Bond cleavage; Bromide; Ligand (biochemistry); Yield (engineering); Medicinal chemistry; Photochemistry; Combinatorial chemistry; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001557215,0.0005117772,0.0002165011,0.0001758612,0.0002300362,0.0002132555,0.000317137,0.0001722301,0.004114802],"category_scores_gemma":[0.0001794202,0.0001312923,0.0001710479,0.0002596395,0.0001742316,0.0002310674,0.0005058007,0.0003969271,0.0008581136],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002791849,"about_ca_system_score_gemma":0.0002450223,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0016106,"about_ca_topic_score_gemma":0.005771389,"domain_scores_codex":[0.9997815,0.00001561964,0.000007144048,0.0000304631,0.00004758715,0.0001176435],"domain_scores_gemma":[0.9999429,0.00000962347,0.00001395253,0.00001007646,0.00001208014,0.00001139294],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002166865,0.0001303426,0.0008572775,0.0004224505,0.00005155589,0.0003273518,0.0001927136,0.0009246618,0.9524662,0.004538329,0.001384348,0.03848811],"study_design_scores_gemma":[0.00002176405,0.0001816488,0.00131702,0.00001010407,0.00002082317,0.0002547594,0.00003124848,0.0009094427,0.9895733,0.000134267,0.007535085,0.00001056223],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9522829,0.002118582,0.008081576,0.00009519086,0.00005862279,0.00003856287,0.0003064481,0.0001950998,0.03682299],"genre_scores_gemma":[0.9921705,0.001363921,0.001458798,0.00003340726,0.00001230769,0.00001795441,0.0002209433,0.00002041333,0.004701756],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004114802,"threshold_uncertainty_score":0.01376539,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005652772029242035,"score_gpt":0.240200181872315,"score_spread":0.234547409843073,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}