{"id":"W2016768966","doi":"10.1021/es0488941","title":"UV Photolytic Mechanism of <i>N</i>-Nitrosodimethylamine in Water:  Dual Pathways to Methylamine versus Dimethylamine","year":2005,"lang":"en","type":"article","venue":"Environmental Science & Technology","topic":"Water Treatment and Disinfection","field":"Environmental Science","cited_by":110,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Ministère de l’Éducation, Gouvernement de l’Ontario","keywords":"Dimethylamine; Chemistry; N-Nitrosodimethylamine; Photodissociation; Methylamine; Photochemistry; Nitrite; Aqueous solution; Carcinogen; Nitrate; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001494353,0.0003375355,0.0001498496,0.00009389361,0.0001186115,0.0001760879,0.0002282569,0.0003163775,0.0007300054],"category_scores_gemma":[0.0001803667,0.0001345513,0.0001971149,0.00006006019,0.0002410426,0.0002715489,0.0001476408,0.0003448238,0.0001880564],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002961259,"about_ca_system_score_gemma":0.0001277559,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004880176,"about_ca_topic_score_gemma":0.0005290678,"domain_scores_codex":[0.9999167,0.00001446783,0.000004342159,0.00002544502,0.00002199197,0.00001724102],"domain_scores_gemma":[0.9999025,0.00003187005,0.00003238452,0.000006025842,0.00001887996,0.000008306284],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003764933,0.000004416207,0.0001220171,0.00002782401,0.000001771631,0.00001854587,0.00001296448,0.00005151857,0.9989225,0.0000567508,0.000006958736,0.0007372018],"study_design_scores_gemma":[0.000001602024,0.0000552312,0.0003332266,9.146461e-7,0.000001880666,0.00002445845,0.000005746585,0.0003042625,0.9990995,0.00001570233,0.0001562669,0.0000012976],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9925931,0.001380838,0.004679205,0.00004952868,0.0000122373,0.00002609813,0.00006393522,0.00002480579,0.00117028],"genre_scores_gemma":[0.9955623,0.000575661,0.002350943,0.00001923853,0.000003762716,0.00001697218,0.00004664802,0.000006270287,0.001418226],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007300054,"threshold_uncertainty_score":0.002442122,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00810656310317273,"score_gpt":0.2126296358674675,"score_spread":0.2045230727642948,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}