{"id":"W2017092433","doi":"10.1021/ic9000335","title":"Conjugated Triarylboryl Donor−Acceptor Systems Supported by 2,2′-Bipyridine: Metal Chelation Impact on Intraligand Charger Transfer Emission, Electron Accepting Ability, and “Turn-on” Fluoride Sensing","year":2009,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":124,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Acceptor; Electrochemistry; Chelation; Photochemistry; Phosphorescence; Molecule; Bipyridine; Metal; Electron acceptor; 2,2'-Bipyridine; Inorganic chemistry; Fluorescence; Crystallography; Crystal structure; Physical chemistry; Organic chemistry; Electrode","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0007708526,0.0005208636,0.000660899,0.00005115451,0.000229047,0.0003454667,0.0002575984,0.0003419277,0.001236855],"category_scores_gemma":[0.0002345735,0.0004100416,0.0001182909,0.0002067923,0.00009760799,0.0003662813,0.00003216263,0.0002963297,0.0000598461],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002617405,"about_ca_system_score_gemma":0.0001296372,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006023082,"about_ca_topic_score_gemma":4.652975e-7,"domain_scores_codex":[0.9971432,0.0001085658,0.0007979166,0.0007910291,0.0004568696,0.0007024395],"domain_scores_gemma":[0.9987829,0.0001159003,0.0002078008,0.000459732,0.0001332528,0.0003004036],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000454691,0.0001236332,0.0003996156,0.00009473279,0.00002739991,0.000009634326,0.0001987479,0.000005046187,0.9968015,0.000002911874,0.001734092,0.0001479925],"study_design_scores_gemma":[0.001317936,0.0001756326,0.001713267,0.0001239168,0.00006939271,0.00006456103,0.00005971642,0.0001329773,0.9957298,0.00002041687,0.0001307527,0.000461635],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9981229,0.0001758158,0.00002114863,0.0003466607,0.0003504783,0.0004706513,0.0001521747,0.0002253875,0.0001347269],"genre_scores_gemma":[0.9987569,0.00005266612,0.00001297831,0.0001433852,0.0005609488,0.000005295414,0.000266583,0.00004428293,0.0001569714],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001639731,"threshold_uncertainty_score":0.9998351,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007771939559641607,"score_gpt":0.2488395773291208,"score_spread":0.2410676377694791,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}