{"id":"W2017217942","doi":"10.1021/jp993162u","title":"Isomerization and Fragmentation Products of CH<sub>2</sub>Cl<sub>2</sub> and Other Dihalomethanes in Rare-Gas Matrices:  An Electron Bombardment Matrix-Isolation FTIR Spectroscopic Study","year":2000,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":40,"is_retracted":false,"has_abstract":true,"ca_institutions":"Trent University; Queen's University","funders":"","keywords":"Matrix isolation; Fragmentation (computing); Isomerization; Rare gas; Fourier transform infrared spectroscopy; Electron; Matrix (chemical analysis); Analytical Chemistry (journal); Chemistry; Materials science; Physical chemistry; Atomic physics; Physics; Infrared spectroscopy; Organic chemistry; Nuclear physics; Computer science; Catalysis; Optics; Chromatography","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001685079,0.0002268089,0.0003949246,0.00003441466,0.00008200132,0.00002549626,0.0001284741,0.00002893211,0.000007799233],"category_scores_gemma":[0.00001051309,0.0001769448,0.00005303762,0.0002930297,0.0001033848,0.0003171598,0.00003961179,0.0002760466,0.000001277821],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005583085,"about_ca_system_score_gemma":0.00002844124,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000009251059,"about_ca_topic_score_gemma":6.917098e-7,"domain_scores_codex":[0.9987576,0.00008188765,0.0004203102,0.000220036,0.0002981687,0.0002220029],"domain_scores_gemma":[0.999155,0.00009788103,0.0004257241,0.0001655677,0.00009033204,0.00006542604],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002139285,0.0007914322,0.001370753,0.00007742158,0.00008944047,6.097452e-7,0.001757375,0.001751915,0.9914159,0.00002647595,0.000004521272,0.002500253],"study_design_scores_gemma":[0.001096755,0.0003385953,0.001665144,0.0000598292,0.000133211,0.000002222958,0.0008159149,0.0003471875,0.9868963,0.008481004,0.000004426087,0.0001593855],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9991489,0.0001827027,0.0001698607,0.00007129188,0.000008500979,0.0002863708,0.00000923597,0.000008113703,0.0001150392],"genre_scores_gemma":[0.9993665,0.00007688968,0.00004943094,0.00000958528,0.0004451852,0.000011831,0.000009578311,0.00002390886,0.000007093613],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008454529,"threshold_uncertainty_score":0.7215601,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006088251595558488,"score_gpt":0.2564453290345537,"score_spread":0.2503570774389952,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}