{"id":"W2017312554","doi":"10.1002/mrc.1256","title":"Methyl TROSY: explanation and experimental verification","year":2003,"lang":"en","type":"article","venue":"Magnetic Resonance in Chemistry","topic":"Protein Structure and Dynamics","field":"Biochemistry, Genetics and Molecular Biology","cited_by":207,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Macromolecule; Deuterium; Relaxation (psychology); Heteronuclear single quantum coherence spectroscopy; Dipole; Nuclear magnetic resonance; Protein dynamics; Pulse sequence; Chemical physics; Analytical Chemistry (journal); Computational chemistry; Molecular dynamics; Nuclear magnetic resonance spectroscopy; Atomic physics; Chromatography; Physics; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.005523471,0.001331362,0.0005944609,0.000861233,0.001218547,0.0009104711,0.003314722,0.001747016,0.006611972],"category_scores_gemma":[0.007247206,0.0005256011,0.0005079688,0.001013576,0.002524096,0.003314895,0.002256217,0.002559512,0.001573499],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0009431501,"about_ca_system_score_gemma":0.0009793754,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001065468,"about_ca_topic_score_gemma":0.0003480894,"domain_scores_codex":[0.9979053,0.000423443,0.0001088715,0.0005146762,0.0007750121,0.0002728013],"domain_scores_gemma":[0.996438,0.0008242169,0.000360252,0.001424288,0.0008409341,0.0001123424],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001836347,0.0007910504,0.006066594,0.001467622,0.000111829,0.002822847,0.0006188509,0.01138315,0.5535032,0.3216511,0.005484855,0.09426261],"study_design_scores_gemma":[0.000252635,0.001594113,0.003851692,0.0002607171,0.00004868671,0.001207394,0.0002882344,0.1076298,0.7318088,0.1227423,0.03009348,0.0002221395],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.2547757,0.003785173,0.6898598,0.004926884,0.001050134,0.0007510147,0.002157987,0.002950298,0.03974306],"genre_scores_gemma":[0.8000177,0.002239341,0.1891529,0.00090617,0.000311738,0.0007604335,0.001083863,0.0002797552,0.005248105],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.006611972,"threshold_uncertainty_score":0.02921128,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005574937273255068,"score_gpt":0.2359708549894148,"score_spread":0.2303959177161597,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}