{"id":"W2017546747","doi":"10.1023/b:tmch.0000019412.93362.a8","title":"The kinetics and mechanism of the oxidation of DL ethionine and thiourea by potassium ferrate","year":2004,"lang":"en","type":"article","venue":"Transition Metal Chemistry","topic":"Advanced oxidation water treatment","field":"Environmental Science","cited_by":10,"is_retracted":false,"has_abstract":false,"ca_institutions":"Mount Allison University","funders":"","keywords":"Chemistry; Thiourea; Organosulfur compounds; Ethionine; Inorganic chemistry; Kinetics; Reaction rate constant; Sulfur; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003453867,0.0002326755,0.0002771695,0.0002365324,0.000158445,0.0003613964,0.0003904711,0.0004428563,0.0009324619],"category_scores_gemma":[0.0005621637,0.0001914169,0.0002385892,0.0001533327,0.0003496612,0.000526997,0.0001228006,0.0003717127,0.0002979457],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007682527,"about_ca_system_score_gemma":0.0002259987,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.004556377,"about_ca_topic_score_gemma":0.0020022,"domain_scores_codex":[0.9998735,0.00002192004,0.000009077114,0.00002445971,0.00002589963,0.00004511547],"domain_scores_gemma":[0.999731,0.000117675,0.00004678142,0.00002534745,0.00005830833,0.00002085004],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001169893,0.00003676964,0.001350883,0.0000983759,0.00001765897,0.00007402625,0.0001339333,0.0007399981,0.9910647,0.0007124798,0.0001022922,0.004499041],"study_design_scores_gemma":[0.00001283031,0.0001569694,0.002745279,0.000004745476,0.0000100235,0.00006252679,0.00004266885,0.004909954,0.9912277,0.0001039632,0.0007121126,0.00001110092],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9964225,0.0007127142,0.001976718,0.00007417885,0.00001239277,0.00001041325,0.0001188574,0.00006108901,0.0006111847],"genre_scores_gemma":[0.9979166,0.0001832831,0.0004582921,0.000008035566,0.00000279813,0.000004274378,0.0001124551,0.000009380507,0.00130476],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004556377,"threshold_uncertainty_score":0.009059727,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005128759157495178,"score_gpt":0.1968835581362909,"score_spread":0.1917547989787957,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}