{"id":"W2017659621","doi":"10.1016/j.poly.2009.05.030","title":"Substituted pyridine coordinated N,N-trans and N,N-cis cyclopalladated complexes of (S)-4-tert-butyl-2-phenyl-2-oxazoline: Crystal structures, spectral study and catalysis of the decomposition of PS pesticides","year":2009,"lang":"en","type":"article","venue":"Polyhedron","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":false,"ca_institutions":"Queen's University","funders":"Beijing Normal University","keywords":"Chemistry; Pyridine; Palladium; Oxazoline; Chloroform; Stereochemistry; Crystal structure; Medicinal chemistry; Cis–trans isomerism; Catalysis; Ring (chemistry); Coordination sphere; Crystallography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006946883,0.000170974,0.0001723624,0.0000813322,0.0001130977,0.0002622011,0.0006523808,0.0001653154,0.001711089],"category_scores_gemma":[0.0001602146,0.0001266217,0.00006622433,0.0001153245,0.0001971788,0.0001860955,0.0001901671,0.0003309853,0.0002069725],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004748421,"about_ca_system_score_gemma":0.0001845409,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001983528,"about_ca_topic_score_gemma":0.002672685,"domain_scores_codex":[0.9999268,0.00001027923,0.000004078577,0.00001778428,0.00002352895,0.00001761296],"domain_scores_gemma":[0.9999627,0.000009983269,0.0000105698,0.000005380416,0.000003727733,0.000007649461],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007410531,0.00005058932,0.0003370133,0.0002070642,0.00002060192,0.0001614715,0.0001080454,0.001087705,0.9913443,0.001381382,0.0003590861,0.004201652],"study_design_scores_gemma":[0.00008354709,0.0003693493,0.001424443,0.000007481756,0.00002085908,0.0002240568,0.00007573137,0.00251873,0.9920272,0.0001001128,0.003137914,0.00001068614],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9939669,0.000539511,0.000783815,0.00003727691,0.00001094632,0.00001040736,0.0001011823,0.00003806826,0.004511832],"genre_scores_gemma":[0.997515,0.0002324045,0.0003379276,0.00001055567,0.000001592005,0.000007205493,0.0001320369,0.000008642157,0.001754856],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001983528,"threshold_uncertainty_score":0.005724192,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008376054704891238,"score_gpt":0.2704298733742805,"score_spread":0.2620538186693893,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}