{"id":"W2017659621","doi":"10.1016/j.poly.2009.05.030","title":"Substituted pyridine coordinated N,N-trans and N,N-cis cyclopalladated complexes of (S)-4-tert-butyl-2-phenyl-2-oxazoline: Crystal structures, spectral study and catalysis of the decomposition of PS pesticides","year":2009,"lang":"en","type":"article","venue":"Polyhedron","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":false,"ca_institutions":"Queen's University","funders":"Beijing Normal University","keywords":"Chemistry; Pyridine; Palladium; Oxazoline; Chloroform; Stereochemistry; Crystal structure; Medicinal chemistry; Cis–trans isomerism; Catalysis; Ring (chemistry); Coordination sphere; Crystallography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001227517,0.0002751331,0.000574699,0.0001153405,0.0001395355,0.00003162993,0.0002442801,0.0001119717,0.00007571938],"category_scores_gemma":[0.00007362761,0.0002316456,0.0001121049,0.000394464,0.0004402639,0.0001135308,0.00007054586,0.0002099267,1.820741e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005863302,"about_ca_system_score_gemma":0.00005805019,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002604819,"about_ca_topic_score_gemma":0.001164287,"domain_scores_codex":[0.9984335,0.000007245406,0.0006833109,0.0003510005,0.0002765122,0.0002484122],"domain_scores_gemma":[0.9987127,0.0001322481,0.0004093318,0.0004990827,0.0001594299,0.00008717003],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002600494,0.0003668091,0.04747373,0.0001535193,0.0002039029,0.000004298176,0.0008394977,0.0002921727,0.9499615,0.0001014344,0.000009506125,0.0003335391],"study_design_scores_gemma":[0.001321296,0.0001152735,0.2693053,0.00008850866,0.0004395057,0.00006076326,0.0003644949,0.001267312,0.7265772,0.0002823314,0.000003390471,0.000174607],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9987792,0.0002901914,0.00006730756,0.0001260073,0.00004580053,0.0002444874,0.0003380099,0.00004972447,0.00005930502],"genre_scores_gemma":[0.9996097,0.00002837451,0.00007798311,0.000005322046,0.00003748842,0.000003641345,0.0001983938,0.00002142493,0.00001767142],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2233844,"threshold_uncertainty_score":0.9446232,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008376054704891238,"score_gpt":0.2704298733742805,"score_spread":0.2620538186693893,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}