{"id":"W2018139764","doi":"10.1002/poc.1484","title":"Absolute reactivity of arylallyl carbocations","year":2008,"lang":"en","type":"article","venue":"Journal of Physical Organic Chemistry","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"","keywords":"Carbocation; Chemistry; Reactivity (psychology); Substituent; Flash photolysis; Solvolysis; Nucleophile; Photochemistry; Medicinal chemistry; Reaction rate constant; Solvent effects; Solvent; Computational chemistry; Organic chemistry; Kinetics; Hydrolysis; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002896382,0.0002982017,0.0002539328,0.0001960289,0.0001312924,0.0002743082,0.0003391614,0.0002772699,0.002066267],"category_scores_gemma":[0.0005925249,0.0001378943,0.0002293787,0.0001345394,0.0002213989,0.0002832966,0.0002131851,0.0003843265,0.0002953759],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003090191,"about_ca_system_score_gemma":0.0001594527,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005015831,"about_ca_topic_score_gemma":0.0007017904,"domain_scores_codex":[0.9997596,0.00003386802,0.00001316471,0.00006344381,0.00006412144,0.00006588914],"domain_scores_gemma":[0.9996468,0.00009630933,0.0001182576,0.00003788539,0.00006612007,0.00003471553],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002266318,0.00000644929,0.0004735509,0.00005924879,0.00001572488,0.00005751057,0.00003102484,0.0002888904,0.9971521,0.0001868492,0.00005095329,0.001451115],"study_design_scores_gemma":[0.00001173196,0.0003040757,0.0009985364,0.000006029886,0.0000109886,0.0001519772,0.00002192241,0.0004387838,0.9971253,0.00003729461,0.0008860693,0.000007300207],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9967439,0.000862727,0.0009662029,0.00002656811,0.00001381038,0.00001168906,0.0001057942,0.00002689164,0.001242384],"genre_scores_gemma":[0.9978403,0.0003493127,0.0005873467,0.00001529547,0.00000534791,0.000007980791,0.0001477815,0.00001088955,0.001035722],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002066267,"threshold_uncertainty_score":0.006912291,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01150258146878578,"score_gpt":0.2308745741962379,"score_spread":0.2193719927274521,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}