{"id":"W2018395682","doi":"10.1021/ja049575c","title":"The Role of Nonbonded Sulfur−Oxygen Interaction in the Dissociative Electron Transfer to Nitro-Substituted Arenesulfenyl Chlorides","year":2004,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"","keywords":"Chemistry; Nitro; Sulfur; Electron transfer; Oxygen; Dissociative; Oxygen atom; Photochemistry; Computational chemistry; Molecule; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002562465,0.0003592443,0.0003123203,0.0001284426,0.0002504268,0.0003318416,0.0004134458,0.0003515626,0.00154604],"category_scores_gemma":[0.0002704585,0.0001734341,0.0001890967,0.0001144844,0.0002988412,0.000319947,0.0002737031,0.0003033017,0.0001724956],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000304207,"about_ca_system_score_gemma":0.00025909,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001006269,"about_ca_topic_score_gemma":0.001586532,"domain_scores_codex":[0.9999124,0.00001683976,0.000003269484,0.000009870868,0.00003116274,0.00002653274],"domain_scores_gemma":[0.9998951,0.00005714942,0.00001637616,0.000005838521,0.0000135875,0.00001193271],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006054501,0.0001687001,0.002357959,0.0003433623,0.00005311652,0.0005091054,0.0002781507,0.01063625,0.966289,0.007471254,0.0001740715,0.0111136],"study_design_scores_gemma":[0.0001171052,0.0008496771,0.004915191,0.00002002287,0.00006976307,0.0002752584,0.0002696516,0.07507005,0.9139593,0.002917877,0.00150241,0.00003366214],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.996151,0.0003386898,0.002011657,0.00006827308,0.00001081915,0.000007127317,0.0000138185,0.00001876033,0.001379937],"genre_scores_gemma":[0.9986807,0.0002468166,0.0004595597,0.00001375696,0.000002272859,0.000004247933,0.00002327408,0.000006549928,0.0005629081],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00154604,"threshold_uncertainty_score":0.005171955,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005433047233132355,"score_gpt":0.2464642060949666,"score_spread":0.2410311588618342,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}