{"id":"W2018576228","doi":"10.1021/ja902982u","title":"Solid-State NMR Investigations of the Immobilization of a BF<sub>4</sub><sup>−</sup>Salt of a Palladium(II) Complex on Silica","year":2009,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Advanced NMR Techniques and Applications","field":"Chemistry","cited_by":36,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Lethbridge","funders":"","keywords":"Chemistry; Palladium; Heteronuclear molecule; Nuclear magnetic resonance spectroscopy; Catalysis; Salt (chemistry); Molecule; Adsorption; Solid-state nuclear magnetic resonance; Ion; Crystallography; Inorganic chemistry; Physical chemistry; Stereochemistry; Organic chemistry; Nuclear magnetic resonance","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001015581,0.0002046202,0.0001496322,0.00008698229,0.0001438734,0.0001695454,0.0002300094,0.0002298591,0.001031184],"category_scores_gemma":[0.0002484565,0.0001411243,0.00009924742,0.0001022685,0.0002019978,0.0001476583,0.00009209202,0.0002361552,0.0003348725],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002239933,"about_ca_system_score_gemma":0.0001376997,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001107991,"about_ca_topic_score_gemma":0.00123637,"domain_scores_codex":[0.9999307,0.00001081319,0.000004071571,0.00001468796,0.00002639535,0.00001338355],"domain_scores_gemma":[0.9998926,0.00003666137,0.00001936141,0.000007732772,0.00002946102,0.00001430734],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005347325,0.000008193603,0.00007728369,0.0000158922,0.000003753316,0.00001984641,0.00001770667,0.00007031037,0.9993312,0.00003095978,0.00001566524,0.000355675],"study_design_scores_gemma":[0.000006640506,0.00009717348,0.00108717,0.000002113423,0.000005955016,0.00003458538,0.00002353263,0.0009703735,0.997263,0.00001474091,0.0004900338,0.000004694033],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9977285,0.0001834209,0.001041432,0.00002990312,0.000006687187,0.000005946783,0.0001013601,0.00002092102,0.0008819205],"genre_scores_gemma":[0.9959217,0.0002057869,0.002061861,0.0000266189,0.000005427674,0.000009312789,0.0002608092,0.00001312752,0.001495199],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001107991,"threshold_uncertainty_score":0.003449678,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01518763998251669,"score_gpt":0.2879235353756303,"score_spread":0.2727358953931136,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}