{"id":"W2018628410","doi":"10.1002/hlca.200490205","title":"Regio‐ and Stereoselective 1,3‐Oxathiolane Formation in the Reaction of Thiolactones with Optically Active Oxiranes","year":2004,"lang":"en","type":"article","venue":"Helvetica Chimica Acta","topic":"Organic Chemistry Cycloaddition Reactions","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"Institute of Particle Physics","funders":"","keywords":"Chemistry; Isobenzofuran; Ring (chemistry); Nucleophile; Stereoselectivity; Optically active; Stereochemistry; Anhydrous; Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009114321,0.0001970609,0.0002219957,0.00006363456,0.0001004375,0.00003568779,0.0001748466,0.0001543964,0.0001019578],"category_scores_gemma":[0.0001466545,0.0001420125,0.00004354787,0.0002414275,0.0001775654,0.0003306314,0.00003019579,0.000428404,0.000005250624],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001404366,"about_ca_system_score_gemma":0.00007113446,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003471987,"about_ca_topic_score_gemma":0.00007415403,"domain_scores_codex":[0.9988978,0.00002885768,0.0002956087,0.0002741192,0.000280495,0.0002231552],"domain_scores_gemma":[0.9990084,0.0002689959,0.0002104264,0.0003525205,0.00009862026,0.0000610811],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002427668,0.0002251437,0.0000499491,0.0001134315,0.00003398569,0.000006317438,0.002457642,0.000001115711,0.996223,0.0004346216,0.00002719294,0.0001848707],"study_design_scores_gemma":[0.001361459,0.00009787187,0.008396111,0.0002214532,0.000077405,0.0007294931,0.004911446,0.00001572833,0.9827163,0.0007963992,0.0004601234,0.0002162744],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9820397,0.00001040146,0.00002955735,0.002312973,0.00001435227,0.0001565538,0.00003961219,0.00005284454,0.01534402],"genre_scores_gemma":[0.9992397,0.0001058801,0.0003653473,0.0000667782,0.0000607408,0.00003832178,0.00006647994,0.00002090147,0.00003577898],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01720009,"threshold_uncertainty_score":0.5791103,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008631051121935223,"score_gpt":0.2150490351276583,"score_spread":0.2064179840057231,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}