{"id":"W2018653674","doi":"10.1016/j.jorganchem.2012.05.018","title":"Coordination and reactivity study of titanium phenoxo complexes containing a bulky bidentate imino-N-heterocyclic carbene ligand","year":2012,"lang":"en","type":"article","venue":"Journal of Organometallic Chemistry","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":false,"ca_institutions":"York University","funders":"Natural Sciences and Engineering Research Council of Canada; Ontario Ministry of Research, Innovation and Science; Canada Foundation for Innovation; York University","keywords":"Chemistry; Carbene; Imine; Carbenoid; Ligand (biochemistry); Denticity; Aryl; Reactivity (psychology); Stereochemistry; Medicinal chemistry; Metal; Catalysis; Organic chemistry; Alkyl; Rhodium","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001772107,0.0002015004,0.0002093074,0.0001731714,0.0002821745,0.0003983439,0.0007945403,0.0003108336,0.00179255],"category_scores_gemma":[0.0002958451,0.0001480077,0.0001084199,0.0001508468,0.0002229646,0.0001272633,0.0002130248,0.0002375306,0.0002287953],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004587985,"about_ca_system_score_gemma":0.0001410011,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003124884,"about_ca_topic_score_gemma":0.002075506,"domain_scores_codex":[0.9998447,0.00002746891,0.000007271557,0.00003235832,0.00003889574,0.00004929455],"domain_scores_gemma":[0.999929,0.00001698803,0.00001781244,0.00001129443,0.00001510902,0.000009816751],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00199915,0.0001591194,0.0012257,0.0002061001,0.00008294114,0.0002283937,0.0002657919,0.001892701,0.9865319,0.001170726,0.00109342,0.005144031],"study_design_scores_gemma":[0.0001641946,0.001157706,0.003507387,0.00001142735,0.00007006324,0.0002271909,0.0001790711,0.007901769,0.9824164,0.0001291469,0.004210607,0.00002505626],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9972761,0.00025837,0.000415518,0.00004135725,0.0000086122,0.000007681004,0.00007267344,0.00002207928,0.001897713],"genre_scores_gemma":[0.9982731,0.0001287233,0.0002496081,0.00001162991,0.000004182753,0.000004867823,0.0001176507,0.000007659482,0.001202487],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003124884,"threshold_uncertainty_score":0.006213427,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01771430095928272,"score_gpt":0.2550532388591267,"score_spread":0.2373389378998439,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}