{"id":"W2018758969","doi":"10.1002/ejic.201000566","title":"Spectroscopic Characterization and Competitive Inhibition Studies of Azide Binding to a Functional NOR Model","year":2010,"lang":"en","type":"article","venue":"European Journal of Inorganic Chemistry","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"National Institutes of Health","keywords":"Chemistry; Azide; Heme; Ferrous; Ferric; Sodium azide; Inorganic chemistry; Hemeprotein; Fourier transform infrared spectroscopy; Valence (chemistry); Photochemistry; Stereochemistry; Organic chemistry; Enzyme","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004615697,0.0001629388,0.0002673942,0.00007282533,0.00007320596,0.0000296862,0.0001340527,0.00004277571,0.000893237],"category_scores_gemma":[0.0004300709,0.0001577896,0.00006534845,0.0001353889,0.00005726192,0.0001578473,0.0001101507,0.0003901912,0.00002283239],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006182006,"about_ca_system_score_gemma":0.00007750429,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":1.520078e-7,"about_ca_topic_score_gemma":4.568255e-7,"domain_scores_codex":[0.9987342,0.00002617922,0.0006062431,0.0001859227,0.0003098799,0.0001375498],"domain_scores_gemma":[0.9985967,0.00004612248,0.0006388829,0.0001667616,0.0004145798,0.0001369953],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000414016,0.00004550712,0.0001140027,0.0001460833,0.00006929861,0.0000193925,0.0003664728,0.00001438571,0.9987353,0.0001795241,0.00004371905,0.0002249079],"study_design_scores_gemma":[0.0006700832,0.00002555041,0.0004099811,0.0001738881,0.00004660047,0.0001860558,0.0004380489,0.00007458244,0.9975858,0.00007388831,0.0001829691,0.0001325527],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9906601,0.00003422386,0.007419401,0.0001494757,0.0001740671,0.00003340267,0.00004577157,0.00001683018,0.001466774],"genre_scores_gemma":[0.9962065,0.00004071495,0.00219878,0.00004433102,0.000392415,8.567053e-7,0.00005192617,0.00003396695,0.001030561],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005546394,"threshold_uncertainty_score":0.9780319,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02082712719660993,"score_gpt":0.2385662009998287,"score_spread":0.2177390738032188,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}