{"id":"W2018969628","doi":"10.1021/ol006463r","title":"Laser Flash Photolysis of Diphenylsulfonyldiazomethane:  Detection of the Sulfene and a Sulfene−Pyridine Ylide","year":2000,"lang":"en","type":"article","venue":"Organic Letters","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Flash photolysis; Pyridine; Photochemistry; Quenching (fluorescence); Ylide; Fluorescence; Stereochemistry; Medicinal chemistry; Optics; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001397569,0.0002787524,0.0001705874,0.0002974192,0.0001857714,0.0001408554,0.0001609936,0.0003920827,0.001348652],"category_scores_gemma":[0.0001837511,0.0001237182,0.00009785611,0.0002001172,0.0002324658,0.0002027593,0.0001649702,0.0003702426,0.0002071783],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003091316,"about_ca_system_score_gemma":0.0002102947,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005716608,"about_ca_topic_score_gemma":0.000857024,"domain_scores_codex":[0.9999299,0.00000874641,0.000002537633,0.00001646019,0.00002387071,0.00001858631],"domain_scores_gemma":[0.9998571,0.00004901493,0.00003400135,0.0000110601,0.00002166536,0.00002711667],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003510647,0.000003671313,0.0001879895,0.00002116459,0.000001533702,0.00003859673,0.00001708481,0.00002047575,0.9990249,0.00005176914,0.00001419397,0.0005834939],"study_design_scores_gemma":[0.000005761583,0.0001561429,0.002647748,0.000003206648,0.000003877236,0.0001322071,0.00002428194,0.0003757669,0.996213,0.00002561547,0.0004098318,0.000002542075],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.995924,0.0008139148,0.001748156,0.00004458589,0.00001062732,0.00001319029,0.000120936,0.00003096777,0.001293598],"genre_scores_gemma":[0.9947128,0.0007591152,0.002196604,0.00004141812,0.000009708405,0.00002547475,0.0002035221,0.000007508265,0.002043834],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001348652,"threshold_uncertainty_score":0.004511654,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004011134927240695,"score_gpt":0.1783629059803482,"score_spread":0.1743517710531075,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}