{"id":"W2019149938","doi":"10.1039/b418772e","title":"Branched [n]rotaxanes (n = 2–4) from multiple dibenzo-24-crown-8 ether wheels and 1,2-bis(4,4′-dipyridinium)ethane axles","year":2005,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":39,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Chemistry; Crown ether; Pyridinium; Dendrimer; Ether; Polymer chemistry; Macromolecule; Axle; Core (optical fiber); Crystallography; Stereochemistry; Medicinal chemistry; Organic chemistry; Materials science; Composite material","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00018067,0.0008856535,0.0007072428,0.00003823023,0.0002440889,0.0002478469,0.0009093707,0.0007873044,0.01202172],"category_scores_gemma":[0.0003681979,0.0009505118,0.000335078,0.0003139067,0.0003972118,0.0002037938,0.0004650298,0.0007066163,0.0001433207],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001525045,"about_ca_system_score_gemma":0.0001746533,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001011754,"about_ca_topic_score_gemma":0.00002314536,"domain_scores_codex":[0.9961829,0.00004955041,0.0007131111,0.001477475,0.000639588,0.0009374439],"domain_scores_gemma":[0.9973297,0.0002022711,0.0003168618,0.001502219,0.0001201356,0.00052888],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001224978,0.0002510462,0.000874947,0.0002959744,0.0002936377,0.0001203332,0.0002750301,0.000001265678,0.9946247,0.000007651424,0.0007097249,0.002423228],"study_design_scores_gemma":[0.00215057,0.00001237737,0.00006196128,0.0001514952,0.000163899,0.0002085981,0.0003585259,0.0002314659,0.9538957,0.0001739212,0.04151943,0.001072026],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9765815,0.007328211,0.004908093,0.00079428,0.0001072722,0.0001528378,0.0002592728,0.000551369,0.009317197],"genre_scores_gemma":[0.9923669,0.0001673723,0.002253403,0.0004428974,0.0009367096,0.00005340591,0.0005759911,0.000199953,0.003003396],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0408097,"threshold_uncertainty_score":0.9992945,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008385231918072486,"score_gpt":0.2043599706031486,"score_spread":0.1959747386850761,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}