{"id":"W2019180388","doi":"10.1007/s00216-014-8092-1","title":"Single-particle speciation of alkylamines in ambient aerosol at five European sites","year":2014,"lang":"en","type":"article","venue":"Analytical and Bioanalytical Chemistry","topic":"Atmospheric chemistry and aerosols","field":"Earth and Planetary Sciences","cited_by":58,"is_retracted":false,"has_abstract":false,"ca_institutions":"Occupational Cancer Research Centre; University of Toronto","funders":"","keywords":"Aerosol; Dimethylamine; Sea salt; Chemistry; Environmental chemistry; Trimethylamine; Nitrate; Diethylamine; Salt (chemistry); Particle (ecology); Mass spectrometry; Triethylamine; Organic chemistry; Chromatography; Ecology","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002357412,0.0001534706,0.0002646325,0.000005085968,0.00005172632,0.00003046699,0.0001282365,0.00007607922,0.001863173],"category_scores_gemma":[0.0002610113,0.0001215709,0.0000775692,0.0002328663,0.0003044301,0.00006522269,0.00004336424,0.0001150657,0.00004980222],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00000858734,"about_ca_system_score_gemma":0.000008204162,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007382258,"about_ca_topic_score_gemma":0.00008872224,"domain_scores_codex":[0.9987563,0.00003812217,0.000369651,0.0003301529,0.0002200992,0.000285609],"domain_scores_gemma":[0.9992861,0.0002226092,0.0000775888,0.0001680221,0.00003523106,0.0002104748],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"observational","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001524269,0.0002600068,0.7598972,0.0002069748,0.00005693621,0.00003955026,0.00008829815,0.0003155015,0.2312343,0.0001081062,0.0003699702,0.007270806],"study_design_scores_gemma":[0.001012672,0.0001880754,0.2008107,0.00008220477,0.0001155884,0.00002954708,0.0002199666,0.1445135,0.6510731,0.0003340973,0.001089359,0.0005311354],"study_design_candidate":"observational","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9723959,0.0000856137,0.00003127155,0.0003944137,0.00001151891,0.00003453562,0.00001483198,0.00001619243,0.02701573],"genre_scores_gemma":[0.9976889,0.00001706151,0.0001259639,0.00009833759,0.0001267553,2.152266e-7,0.00005296318,0.000003515956,0.001886301],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.5590864,"threshold_uncertainty_score":0.9990492,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01373545038039379,"score_gpt":0.2005997864417546,"score_spread":0.1868643360613608,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}