{"id":"W2019330934","doi":"10.1002/chin.200949014","title":"ChemInform Abstract: Electrochemical and Chemical Reduction of Disulfur Dinitride: Formation of [S<sub>4</sub>N<sub>4</sub>]<sup>‐</sup><sup>·</sup>, EPR Spectroscopic Characterization of the [S<sub>2</sub>N<sub>2</sub>H]<sup>·</sup> Radical, and X‐Ray Structure of [Na(15‐crown‐5)][S<sub>3</sub>N<sub>3</sub>].","year":2009,"lang":"en","type":"article","venue":"ChemInform","topic":"Inorganic Chemistry and Materials","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary; University of Lethbridge","funders":"","keywords":"Chemistry; Characterization (materials science); Electrochemistry; X-ray; Electron paramagnetic resonance; Physical chemistry; Nanotechnology; Nuclear magnetic resonance; Optics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001767377,0.0004397975,0.0002465634,0.0002981451,0.0002573905,0.0003107018,0.0003962464,0.0003960818,0.01688278],"category_scores_gemma":[0.0002379643,0.0001796088,0.000168458,0.0003254548,0.0001709825,0.0004396392,0.0001866697,0.0004239302,0.002756848],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005549322,"about_ca_system_score_gemma":0.000442,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001071485,"about_ca_topic_score_gemma":0.002323755,"domain_scores_codex":[0.9998453,0.0000105515,0.000007024033,0.00002668694,0.000097382,0.00001304208],"domain_scores_gemma":[0.9999224,0.00001376584,0.00001324041,0.000009313968,0.00003139692,0.000009937206],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006186183,0.00009891031,0.0005061801,0.0006100686,0.00003985757,0.0001693437,0.0000814235,0.000426361,0.9481013,0.001593818,0.01537902,0.03237519],"study_design_scores_gemma":[0.00001312022,0.000070361,0.0008159148,0.000006650452,0.00001326121,0.0001054493,0.00001946133,0.0005530678,0.984277,0.0001302778,0.01398789,0.000007530316],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7775569,0.009112468,0.0368616,0.002226101,0.001905839,0.0002487365,0.01131043,0.002657084,0.1581209],"genre_scores_gemma":[0.8672142,0.005022809,0.01684678,0.0005147895,0.0001784982,0.00006406484,0.01226804,0.0002951794,0.09759572],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01688278,"threshold_uncertainty_score":0.0564785,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005403067255386224,"score_gpt":0.1995766098036349,"score_spread":0.1941735425482486,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}