{"id":"W2019330934","doi":"10.1002/chin.200949014","title":"ChemInform Abstract: Electrochemical and Chemical Reduction of Disulfur Dinitride: Formation of [S<sub>4</sub>N<sub>4</sub>]<sup>‐</sup><sup>·</sup>, EPR Spectroscopic Characterization of the [S<sub>2</sub>N<sub>2</sub>H]<sup>·</sup> Radical, and X‐Ray Structure of [Na(15‐crown‐5)][S<sub>3</sub>N<sub>3</sub>].","year":2009,"lang":"en","type":"article","venue":"ChemInform","topic":"Inorganic Chemistry and Materials","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary; University of Lethbridge","funders":"","keywords":"Chemistry; Characterization (materials science); Electrochemistry; X-ray; Electron paramagnetic resonance; Physical chemistry; Nanotechnology; Nuclear magnetic resonance; Optics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity"],"consensus_categories":["metaepi_narrow","research_integrity"],"category_scores_codex":[0.001392054,0.003375161,0.004316853,0.0007282357,0.0008347422,0.0004515753,0.002251785,0.003910591,0.0001883293],"category_scores_gemma":[0.00163626,0.003333774,0.001440148,0.002226851,0.002238176,0.003030397,0.001084809,0.003224903,0.00005225304],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00153061,"about_ca_system_score_gemma":0.001271761,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001778699,"about_ca_topic_score_gemma":0.00000637383,"domain_scores_codex":[0.9838617,0.00004251731,0.006822041,0.00280412,0.003146744,0.003322903],"domain_scores_gemma":[0.9877642,0.0006051908,0.005425276,0.003247614,0.001556384,0.001401284],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002119498,0.0009668942,0.00008974536,0.006175896,0.0005996391,0.00002699091,0.003498487,0.00005358084,0.9489722,0.00009845122,0.001963322,0.03543536],"study_design_scores_gemma":[0.006327107,0.0004187695,0.0007818068,0.001891512,0.001288681,0.001002199,0.001283653,0.000745128,0.9823433,0.0007318181,0.0002754744,0.002910538],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9922839,0.0005223115,0.00004156082,0.0003692549,0.0003459392,0.002184695,0.001697176,0.000496743,0.002058385],"genre_scores_gemma":[0.987652,0.003820245,0.0001056351,0.0002433971,0.00180426,0.0002185669,0.005680723,0.0004323445,0.00004281744],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03337118,"threshold_uncertainty_score":0.9990747,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005403067255386224,"score_gpt":0.1995766098036349,"score_spread":0.1941735425482486,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}