{"id":"W2019569613","doi":"10.1002/bip.21103","title":"Benzophenone semicarbazone protection strategy for synthesis of aza‐glycine containing aza‐peptides","year":2008,"lang":"en","type":"article","venue":"Biopolymers","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":30,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Peptide; Tripeptide; Dipeptide; Combinatorial chemistry; Benzophenone; Hydrazone; Peptidomimetic; Stereochemistry; Amino acid; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001132718,0.0001690914,0.0002912565,0.00005260948,0.0001066336,0.000006970571,0.0001330049,0.0001581605,0.00003974125],"category_scores_gemma":[0.0001786921,0.0001540606,0.0002412501,0.0001277029,0.000154779,0.000004358858,0.00003650904,0.00004848865,0.00000198595],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001563332,"about_ca_system_score_gemma":0.00005010881,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001839881,"about_ca_topic_score_gemma":0.00001574698,"domain_scores_codex":[0.9989762,0.0000280249,0.0003023811,0.0003332014,0.0001219215,0.0002382445],"domain_scores_gemma":[0.9993939,0.00003955182,0.0001641477,0.0002411143,0.00008034653,0.00008087721],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002450852,0.00008165355,0.0004331226,0.00003335626,0.0001656906,8.981581e-7,0.00001746814,0.00001858466,0.9864568,0.00002309553,0.0001489554,0.01237526],"study_design_scores_gemma":[0.0003572111,0.0003467386,0.000307275,0.0000278918,0.00008280289,0.000009011491,0.000187345,0.0001075312,0.9975664,0.00001659286,0.0008017787,0.0001894349],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9964553,0.001106377,0.001435257,0.0001099957,0.00003530076,0.0002138937,0.00007494451,0.00001632443,0.000552662],"genre_scores_gemma":[0.998629,0.0002059323,0.0004978834,0.00003824296,0.0002081642,0.00008948203,0.00006081374,0.00002547139,0.0002450011],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01218583,"threshold_uncertainty_score":0.6282407,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02774804405164451,"score_gpt":0.2467785313089382,"score_spread":0.2190304872572937,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}