{"id":"W2019656416","doi":"10.1002/ejoc.200600819","title":"A Mechanistic Study on the Catalytic, Asymmetric α‐Bromination of Acid Chlorides","year":2007,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Vanadium and Halogenation Chemistry","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brock University","funders":"","keywords":"Chemistry; Halogenation; Kinetic resolution; Catalysis; Enantiomer; Derivatization; Enantiomeric excess; Organic chemistry; Enantioselective synthesis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004378709,0.000283895,0.0002822519,0.00008879147,0.0001744661,0.0002487157,0.0005800098,0.0002990735,0.001063683],"category_scores_gemma":[0.0002954252,0.0001051228,0.0001788736,0.00006382823,0.0003307097,0.0003842472,0.0002009193,0.0005340078,0.0002680388],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002453826,"about_ca_system_score_gemma":0.0002155477,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004131698,"about_ca_topic_score_gemma":0.0003329733,"domain_scores_codex":[0.9998257,0.00004012786,0.000009033113,0.00002618893,0.00004895346,0.00005006396],"domain_scores_gemma":[0.9999154,0.00003104883,0.00001783338,0.00001167339,0.00001417686,0.000009825048],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003218759,0.0001340889,0.0001971465,0.0002859508,0.0000147679,0.0003818111,0.0001331955,0.001246104,0.9882593,0.003127566,0.0001449065,0.005753365],"study_design_scores_gemma":[0.00003211581,0.0002973621,0.0002662323,0.000006306404,0.000009346421,0.0001731375,0.00003052114,0.001762807,0.9952524,0.0002705858,0.001892851,0.000006292281],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9798179,0.001737101,0.009947371,0.0002105597,0.00004872829,0.00009383322,0.0001038471,0.00005566256,0.007985033],"genre_scores_gemma":[0.9974282,0.0005954896,0.001123898,0.00003480331,0.000007811685,0.00001102303,0.00002893856,0.000004259446,0.0007654456],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001063683,"threshold_uncertainty_score":0.003558338,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01759624982448285,"score_gpt":0.231893551622892,"score_spread":0.2142973017984091,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}