{"id":"W2019669095","doi":"10.1021/ja030277+","title":"The Kinetics of Helix Unfolding of an Azobenzene Cross-Linked Peptide Probed by Nanosecond Time-Resolved Optical Rotatory Dispersion","year":2003,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Photoreceptor and optogenetics research","field":"Neuroscience","cited_by":56,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"National Institute of General Medical Sciences; National Institutes of Health","keywords":"Photoisomerization; Chemistry; Azobenzene; Optical rotatory dispersion; Nanosecond; Helix (gastropod); Kinetics; Crystallography; Folding (DSP implementation); Peptide; Cis–trans isomerism; Time constant; Circular dichroism; Stereochemistry; Molecule; Isomerization; Laser; Optics; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001413062,0.0002025834,0.0001431899,0.00007039014,0.00008168305,0.0001960521,0.0001320122,0.0001557536,0.0006181555],"category_scores_gemma":[0.0002994027,0.00008936655,0.00008508127,0.00008244117,0.0001735721,0.0002105152,0.0000904222,0.0003756536,0.0002122857],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002873662,"about_ca_system_score_gemma":0.00009068264,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004962743,"about_ca_topic_score_gemma":0.0004807752,"domain_scores_codex":[0.9999301,0.000006830994,0.00000272346,0.00002069903,0.00002607282,0.00001343185],"domain_scores_gemma":[0.9998288,0.00006378967,0.00005497272,0.000008423621,0.00002262549,0.00002133754],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007009191,0.00001245663,0.0004645083,0.00001876581,0.000004245983,0.00001470228,0.00003439084,0.0002352013,0.9976522,0.00007008576,0.00001516139,0.001408283],"study_design_scores_gemma":[0.000006909007,0.0002235876,0.006118596,0.00000442211,0.000006157869,0.00007345049,0.00002763297,0.005078317,0.9876714,0.00005523356,0.0007254556,0.000008896792],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.995822,0.0004488131,0.002927472,0.00001912428,0.000007700087,0.00001228431,0.00009127043,0.00004072755,0.000630731],"genre_scores_gemma":[0.9968177,0.0004272885,0.001647931,0.00001524997,0.000003285784,0.00001719221,0.0001301268,0.00001579512,0.0009252874],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006181555,"threshold_uncertainty_score":0.00208503,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01597757045247629,"score_gpt":0.2991551634181396,"score_spread":0.2831775929656633,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}