{"id":"W2019736372","doi":"10.1007/s12039-011-0172-6","title":"η 5 and η 6 - cyclic π-perimeter hydrocarbon platinum group metal complexes of 3-(2-pyridyl)pyrazole derived ligands with a pendant nitrile group: Syntheses, spectral and structural studies","year":2012,"lang":"en","type":"article","venue":"Journal of Chemical Sciences","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":false,"ca_institutions":"McMaster University","funders":"","keywords":"Benzonitrile; Chemistry; Nitrile; Pyrazole; Pyridine; Metal; Medicinal chemistry; Stereochemistry; Acetylene; Platinum; Methanol; Crystal structure; Crystallography; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004080073,0.0002225839,0.0006687716,0.00009593575,0.0001239787,0.0000594981,0.0002649964,0.00005254332,0.0004707384],"category_scores_gemma":[0.0002083143,0.0001338748,0.0001262329,0.000212886,0.0009372683,0.0004454911,0.0001423567,0.0001670928,3.772599e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000327616,"about_ca_system_score_gemma":0.00002321571,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003910947,"about_ca_topic_score_gemma":0.000007108873,"domain_scores_codex":[0.9983844,0.00001812343,0.0004999411,0.0002168463,0.0005318546,0.0003488429],"domain_scores_gemma":[0.9986168,0.0005445902,0.0004693283,0.0001149225,0.0000492593,0.0002050853],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007455207,0.00006547914,0.02009928,0.00008413481,0.0002439141,0.000003880833,0.0005669384,5.426492e-7,0.9771839,0.00008863337,0.000004647186,0.001584133],"study_design_scores_gemma":[0.0003369075,0.0001476987,0.00608253,0.0001435997,0.0002838903,0.0004621274,0.001665805,0.00008869477,0.9900429,0.0004332994,0.00008933595,0.0002232164],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9898128,0.009527762,0.000004614014,0.00009190397,0.00003819778,0.00003164563,0.00001164013,0.00000865427,0.0004727944],"genre_scores_gemma":[0.9982424,0.0002194112,0.00129238,0.00001174251,0.0002112421,0.000001683138,0.000001545782,0.00001044982,0.000009174017],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01401675,"threshold_uncertainty_score":0.5459257,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0257011488804753,"score_gpt":0.2600400413992008,"score_spread":0.2343388925187255,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}