{"id":"W2019742631","doi":"10.1007/s10870-004-7724-2","title":"Unique coordination in metal nitroprussides: The structure of Cu[Fe(CN)5NO]?2H2O and Cu[Fe(CN)5NO]","year":2004,"lang":"en","type":"article","venue":"Journal of Chemical Crystallography","topic":"X-ray Diffraction in Crystallography","field":"Materials Science","cited_by":37,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Guelph","funders":"","keywords":"Orthorhombic crystal system; Chemistry; Crystallography; Crystal structure; Tetragonal crystal system; Organometallic chemistry; Metal; Copper; Anhydrous; Rietveld refinement; Hydrate; Atom (system on chip)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001250003,0.0001409772,0.000268163,0.0001114877,0.0002993385,0.0002672017,0.0006101842,0.0002701555,0.0005930968],"category_scores_gemma":[0.0001356693,0.000185219,0.00005833097,0.0001044276,0.0003532914,0.0001472664,0.000227411,0.0002355869,0.00009352071],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003377274,"about_ca_system_score_gemma":0.00020359,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002522729,"about_ca_topic_score_gemma":0.003670475,"domain_scores_codex":[0.9999239,0.00001212674,0.000003346699,0.00002196796,0.00002217437,0.00001650426],"domain_scores_gemma":[0.9999533,0.000004923392,0.00001145902,0.000005794704,0.000007593713,0.0000169279],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001030559,0.00007454823,0.001543429,0.0003916757,0.00004649351,0.0008142328,0.0003385358,0.003597284,0.9717881,0.005148247,0.001864879,0.0133621],"study_design_scores_gemma":[0.0006408795,0.00119729,0.01866069,0.0000440852,0.0001249781,0.002624316,0.0005126075,0.03419128,0.900965,0.004371869,0.03657916,0.00008779647],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9940865,0.0007602226,0.001453057,0.0001494465,0.00003207789,0.00001365715,0.00006301729,0.00006532241,0.003376697],"genre_scores_gemma":[0.9971883,0.0002313357,0.001266955,0.00004752355,0.000009183351,0.000006676151,0.0001145766,0.000008710557,0.001126786],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002522729,"threshold_uncertainty_score":0.005016029,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008094935315114675,"score_gpt":0.2418771375435002,"score_spread":0.2337822022283855,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}