{"id":"W2020077403","doi":"10.1021/ac001192j","title":"Development of Rotating Electrochemical Detectors for Capillary Electrophoresis","year":2001,"lang":"en","type":"article","venue":"Analytical Chemistry","topic":"Microfluidic and Capillary Electrophoresis Applications","field":"Engineering","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada; Biotechnology Research Institute","funders":"","keywords":"Chemistry; Capillary electrophoresis; Pentachlorophenol; Amperometry; Detection limit; Electrode; Working electrode; Analytical Chemistry (journal); Chromatography; Catechol; Electrochemistry; Passivation; Electrophoresis; Analyte; Environmental chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00605677,0.00239918,0.001934621,0.001611885,0.0005567635,0.001631309,0.004130189,0.002654904,0.001694694],"category_scores_gemma":[0.01012455,0.001507042,0.0006578618,0.0009409295,0.0009694198,0.001705157,0.001085523,0.002188323,0.002454692],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001135681,"about_ca_system_score_gemma":0.001246161,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008762926,"about_ca_topic_score_gemma":0.001182153,"domain_scores_codex":[0.9945328,0.001449169,0.0003543703,0.001138857,0.002271476,0.0002533368],"domain_scores_gemma":[0.9951168,0.002039553,0.0003312785,0.0002844947,0.002001034,0.0002268408],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001423534,0.00008201817,0.0004863095,0.0006496118,0.00006032986,0.0002037848,0.00006990768,0.0009101292,0.9143597,0.002871723,0.001544098,0.07862015],"study_design_scores_gemma":[0.00005714786,0.0004819362,0.0006808436,0.00007947553,0.00007527514,0.001200465,0.00002867066,0.01674953,0.9464247,0.0004970095,0.03360235,0.0001225834],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.02874633,0.01610806,0.9432327,0.0007428982,0.0009865662,0.001329093,0.0004263661,0.004943713,0.003484284],"genre_scores_gemma":[0.05190907,0.004566467,0.9392526,0.00038001,0.0001083612,0.0007311896,0.0004232683,0.0001317418,0.002497208],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.00605677,"threshold_uncertainty_score":0.03203166,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008304931723479082,"score_gpt":0.2182822144412952,"score_spread":0.2099772827178162,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}