{"id":"W2020240051","doi":"10.1021/ic701822n","title":"Pyridine−<i>tert</i>-Nitrogen−Phenol Ligands: N,N,O-Type Tripodal Chelates for the [M(CO)<sub>3</sub>]<sup>+</sup> Core (M = Re, Tc)","year":2008,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Radiopharmaceutical Chemistry and Applications","field":"Medicine","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia; TRIUMF","funders":"","keywords":"Chemistry; Chelation; Pyridine; Rhenium; Phenol; Nitrogen atom; Metal; Monomer; Nitrogen; Stereochemistry; Cysteine; Medicinal chemistry; Inorganic chemistry; Organic chemistry; Enzyme; Ring (chemistry)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001806626,0.0004321359,0.0004899792,0.00001744388,0.0005163002,0.00003303042,0.000460838,0.0003774645,0.0004877416],"category_scores_gemma":[0.0004103171,0.0003422722,0.0003033664,0.0004901897,0.0004021011,0.00007094953,0.00007904627,0.0007294295,0.0001347603],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00016286,"about_ca_system_score_gemma":0.0003470406,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000003968952,"about_ca_topic_score_gemma":2.234431e-7,"domain_scores_codex":[0.9977896,0.000007555538,0.0005720698,0.0006369341,0.00037827,0.000615544],"domain_scores_gemma":[0.9978527,0.0004203033,0.0001606177,0.0009059911,0.0002425905,0.0004177792],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003004938,0.000272205,0.001598348,0.0003053999,0.0002368483,0.00004169602,0.0002408137,0.00003008519,0.9758786,0.0000107454,0.02060254,0.0004822094],"study_design_scores_gemma":[0.002425298,0.00006233432,0.0001577853,0.00006039126,0.0003982857,0.00090004,0.0002157763,0.001999391,0.9684607,0.0002072885,0.02475588,0.0003568242],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9925057,0.001894124,0.00007317252,0.00257495,0.00005945046,0.0006786121,0.000100396,0.0002566979,0.001856839],"genre_scores_gemma":[0.994858,0.0008068493,0.000104484,0.001118054,0.001494267,0.0001943196,0.0003002374,0.0000908138,0.001032922],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007417918,"threshold_uncertainty_score":0.9999029,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0453752222741591,"score_gpt":0.2958252686023828,"score_spread":0.2504500463282237,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}