{"id":"W2020240051","doi":"10.1021/ic701822n","title":"Pyridine−<i>tert</i>-Nitrogen−Phenol Ligands: N,N,O-Type Tripodal Chelates for the [M(CO)<sub>3</sub>]<sup>+</sup> Core (M = Re, Tc)","year":2008,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Radiopharmaceutical Chemistry and Applications","field":"Medicine","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia; TRIUMF","funders":"","keywords":"Chemistry; Chelation; Pyridine; Rhenium; Phenol; Nitrogen atom; Metal; Monomer; Nitrogen; Stereochemistry; Cysteine; Medicinal chemistry; Inorganic chemistry; Organic chemistry; Enzyme; Ring (chemistry)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001050968,0.0003459875,0.0001718245,0.00007084131,0.0001375384,0.0002343212,0.000511562,0.0002824552,0.001349565],"category_scores_gemma":[0.0001895117,0.0001337196,0.0000890197,0.0001127644,0.0002343183,0.0002343846,0.0002031225,0.0004264608,0.0009379198],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004035583,"about_ca_system_score_gemma":0.0001774418,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003476564,"about_ca_topic_score_gemma":0.0006688919,"domain_scores_codex":[0.999935,0.00001378564,0.000003567508,0.00001744242,0.00001833941,0.00001179153],"domain_scores_gemma":[0.9999044,0.00001777127,0.00003396932,0.00001284962,0.00001248265,0.00001844676],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001167667,0.00001883948,0.00009922196,0.0001144823,0.000003693599,0.000076064,0.00003285952,0.0002468145,0.9940222,0.0005449823,0.000129278,0.004594797],"study_design_scores_gemma":[0.00001278482,0.0001231551,0.0003660848,0.000004384391,0.00000614669,0.000287008,0.00001192808,0.0007410931,0.9938126,0.00005588665,0.004573654,0.000005278991],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9244342,0.003204017,0.0613338,0.0002409168,0.00005255665,0.0001960202,0.0003283958,0.00068052,0.009529669],"genre_scores_gemma":[0.947202,0.001483351,0.0437909,0.0001871659,0.00001624587,0.0001675485,0.0002636087,0.00008568451,0.006803532],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001349565,"threshold_uncertainty_score":0.004514754,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0453752222741591,"score_gpt":0.2958252686023828,"score_spread":0.2504500463282237,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}