{"id":"W2020558577","doi":"10.1021/bc200259c","title":"Quantification of Primary Amine Groups Available for Subsequent Biofunctionalization of Polymer Surfaces","year":2011,"lang":"en","type":"article","venue":"Bioconjugate Chemistry","topic":"Polymer Surface Interaction Studies","field":"Materials Science","cited_by":212,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada; Polytechnique Montréal","funders":"","keywords":"Chemistry; Aminolysis; Amine gas treating; Polymer chemistry; Derivatization; Reagent; Polymer; Contact angle; Ninhydrin; Surface modification; Ethylenediamine; Adsorption; Organic chemistry; Amino acid; Chemical engineering","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003769707,0.0009444481,0.000348642,0.0004377317,0.0001435503,0.0003428209,0.0002684731,0.0005973228,0.001034522],"category_scores_gemma":[0.0006263571,0.0002276052,0.0002680049,0.0002829023,0.0002204934,0.0004495721,0.0002570229,0.0005811971,0.0004529061],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002831643,"about_ca_system_score_gemma":0.0001375932,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002464877,"about_ca_topic_score_gemma":0.0004502746,"domain_scores_codex":[0.9996507,0.00006206207,0.00001807734,0.0001025015,0.0001226434,0.00004398766],"domain_scores_gemma":[0.9995721,0.0001439202,0.0001049287,0.00003150756,0.000114139,0.0000333551],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000007133693,0.000002873624,0.00004670003,0.00003131055,0.000001896698,0.000006410855,0.000004032667,0.00001273917,0.9993144,0.00000977866,0.000004594211,0.0005581461],"study_design_scores_gemma":[7.99453e-7,0.00004585709,0.001024486,0.000006201781,0.000006981267,0.0000385147,0.000007266635,0.0002261593,0.9980518,0.00001550106,0.0005747321,0.000001758715],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8922101,0.0150991,0.08841173,0.0001287612,0.0001115278,0.0001775847,0.0007429756,0.0002776599,0.002840599],"genre_scores_gemma":[0.9052171,0.01085878,0.07504405,0.0001835908,0.00005358396,0.0002863181,0.001705825,0.00009797086,0.006552691],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001034522,"threshold_uncertainty_score":0.003460824,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.06407175323001578,"score_gpt":0.2542008660506279,"score_spread":0.1901291128206121,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}