{"id":"W2020558577","doi":"10.1021/bc200259c","title":"Quantification of Primary Amine Groups Available for Subsequent Biofunctionalization of Polymer Surfaces","year":2011,"lang":"en","type":"article","venue":"Bioconjugate Chemistry","topic":"Polymer Surface Interaction Studies","field":"Materials Science","cited_by":212,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada; Polytechnique Montréal","funders":"","keywords":"Chemistry; Aminolysis; Amine gas treating; Polymer chemistry; Derivatization; Reagent; Polymer; Contact angle; Ninhydrin; Surface modification; Ethylenediamine; Adsorption; Organic chemistry; Amino acid; Chemical engineering","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000239372,0.00013609,0.0002543184,0.000031823,0.00005559705,0.000009878472,0.0001620225,0.00007924084,0.001668379],"category_scores_gemma":[0.00005736881,0.0001287913,0.00007609867,0.0001170513,0.0002067344,0.0001711376,0.00004697638,0.00003131694,0.00004999381],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004661519,"about_ca_system_score_gemma":0.00006611455,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002167614,"about_ca_topic_score_gemma":0.000002984536,"domain_scores_codex":[0.9988633,0.00001872886,0.0004891061,0.000279581,0.0001854172,0.0001638317],"domain_scores_gemma":[0.9988555,0.00007046025,0.0004663769,0.00028206,0.0002863338,0.00003921828],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001606739,0.0001343366,0.002046043,0.0003577885,0.00002903056,1.533587e-7,0.0001507221,0.000003159105,0.9962583,0.0001246158,0.0006889862,0.00004618125],"study_design_scores_gemma":[0.000283047,0.00003299012,0.001187796,0.00004251462,0.00003153607,0.00000225537,0.0001425051,0.00003175207,0.9973736,0.00006041241,0.0006881986,0.0001233551],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9929974,0.001587477,0.001250034,0.00003177541,0.0003404339,0.0001952774,0.0002158423,0.0000472768,0.003334479],"genre_scores_gemma":[0.9961205,0.00006754535,0.0007707296,0.00001845178,0.00003687467,0.00005212158,0.00009510476,0.00001629301,0.002822351],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003123124,"threshold_uncertainty_score":0.9992442,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.06407175323001578,"score_gpt":0.2542008660506279,"score_spread":0.1901291128206121,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}