{"id":"W2020767222","doi":"10.1021/ie070587r","title":"Reaction Kinetics of CO<sub>2</sub> in Aqueous 1-Amino-2-Propanol, 3-Amino-1-Propanol, and Dimethylmonoethanolamine Solutions in the Temperature Range of 298−313 K Using the Stopped-Flow Technique","year":2008,"lang":"en","type":"article","venue":"Industrial & Engineering Chemistry Research","topic":"Carbon Dioxide Capture Technologies","field":"Engineering","cited_by":99,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Regina","funders":"Natural Resources Canada; Natural Sciences and Engineering Research Council of Canada","keywords":"Zwitterion; Chemistry; Aqueous solution; Alkanolamine; Reaction rate constant; Propanol; Amine gas treating; 1-Propanol; Kinetics; Chemical kinetics; Reaction mechanism; Reaction rate; Catalysis; Inorganic chemistry; Physical chemistry; Organic chemistry; Ethanol; Molecule","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity"],"consensus_categories":[],"category_scores_codex":[0.001208843,0.0003238886,0.0004692249,0.0004238639,0.00005324492,0.00002978663,0.0006029812,0.0008252617,0.000002426548],"category_scores_gemma":[0.001205983,0.0002641733,0.00008269416,0.001673278,0.0004724866,0.000116587,0.0001740345,0.002724598,4.129024e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003508058,"about_ca_system_score_gemma":0.00009855923,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001012948,"about_ca_topic_score_gemma":0.00001219158,"domain_scores_codex":[0.9976723,0.000113707,0.0005714998,0.0003350276,0.0006450136,0.0006625036],"domain_scores_gemma":[0.9984137,0.0005584753,0.00008284919,0.0007342739,0.000152982,0.00005776571],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003439871,0.00005757283,0.0003296912,0.0002032522,0.00002584077,0.00005480439,0.00026682,0.01257558,0.9854941,0.000009085774,0.0001083312,0.0008404567],"study_design_scores_gemma":[0.0006857403,0.00006057741,0.001045256,0.0002869527,0.00001450067,0.0002164832,0.0003368547,0.00827167,0.9887196,0.00001469216,0.0001154165,0.0002321914],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9967988,0.001696063,0.00006582547,0.0001250394,0.00009883562,0.0008996954,0.00003968523,0.0001773047,0.00009878381],"genre_scores_gemma":[0.9989388,0.0004727232,0.0001325119,0.000001535534,0.0001804621,0.0001909593,0.00001196448,0.00006044962,0.00001061809],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00430391,"threshold_uncertainty_score":0.999981,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.07642466373651867,"score_gpt":0.2842498600376924,"score_spread":0.2078251963011737,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}