{"id":"W2020767222","doi":"10.1021/ie070587r","title":"Reaction Kinetics of CO<sub>2</sub> in Aqueous 1-Amino-2-Propanol, 3-Amino-1-Propanol, and Dimethylmonoethanolamine Solutions in the Temperature Range of 298−313 K Using the Stopped-Flow Technique","year":2008,"lang":"en","type":"article","venue":"Industrial & Engineering Chemistry Research","topic":"Carbon Dioxide Capture Technologies","field":"Engineering","cited_by":99,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Regina","funders":"Natural Resources Canada; Natural Sciences and Engineering Research Council of Canada","keywords":"Zwitterion; Chemistry; Aqueous solution; Alkanolamine; Reaction rate constant; Propanol; Amine gas treating; 1-Propanol; Kinetics; Chemical kinetics; Reaction mechanism; Reaction rate; Catalysis; Inorganic chemistry; Physical chemistry; Organic chemistry; Ethanol; Molecule","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003671259,0.0005281483,0.0004247927,0.0002653993,0.0002032302,0.0002888908,0.0004843163,0.0006086674,0.0004857516],"category_scores_gemma":[0.0006294046,0.0002356808,0.0002442901,0.000242295,0.00033174,0.0004770562,0.0001239256,0.0005310688,0.0002199462],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006482271,"about_ca_system_score_gemma":0.0003748612,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001705293,"about_ca_topic_score_gemma":0.001899314,"domain_scores_codex":[0.9998237,0.00002539723,0.00001186758,0.00005001576,0.00005467453,0.00003426787],"domain_scores_gemma":[0.9995551,0.0001954351,0.0000902592,0.0000165328,0.0001108508,0.00003200273],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001250305,0.0000108204,0.0003723374,0.00006045612,0.000008028172,0.00002532044,0.00002437252,0.000176316,0.9981591,0.00004111979,0.00001809582,0.0009790091],"study_design_scores_gemma":[0.000004388938,0.00006474523,0.001194918,0.000002416128,0.00000681756,0.00003173374,0.000008804658,0.002512595,0.9958959,0.00001346331,0.000257183,0.000007164994],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9918743,0.001006162,0.006092116,0.00007911123,0.00003070199,0.00004457125,0.0001845612,0.0001411584,0.000547339],"genre_scores_gemma":[0.9905555,0.001130846,0.006565237,0.00003692007,0.000009979164,0.00007717896,0.0003111739,0.00003104704,0.001282003],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001705293,"threshold_uncertainty_score":0.004703283,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.07642466373651867,"score_gpt":0.2842498600376924,"score_spread":0.2078251963011737,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}