{"id":"W2020924347","doi":"10.1021/ic000118g","title":"Tetrachloro- and Tetrabromoarsonium(V) Cations:  Raman and <sup>75</sup>As, <sup>19</sup>F NMR Spectroscopic Characterization and X-ray Crystal Structures of [AsCl<sub>4</sub>][As(OTeF<sub>5</sub>)<sub>6</sub>] and [AsBr<sub>4</sub>][AsF(OTeF<sub>5</sub>)<sub>5</sub>]","year":2000,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Crystallography; Crystal structure; Raman spectroscopy; Nuclear magnetic resonance spectroscopy; Salt (chemistry); X-ray crystallography; Single crystal; Stereochemistry; Diffraction; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001560634,0.000297131,0.0001362604,0.0002043165,0.0001872646,0.0002941876,0.0004172676,0.0004948166,0.001567687],"category_scores_gemma":[0.0002456712,0.0001517846,0.0001277279,0.0002168717,0.0002952368,0.0002128888,0.0002371633,0.0002758595,0.0004412635],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002848262,"about_ca_system_score_gemma":0.000218409,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00162871,"about_ca_topic_score_gemma":0.003098747,"domain_scores_codex":[0.9997936,0.00001590422,0.000009404338,0.00004766489,0.0001034707,0.00002995993],"domain_scores_gemma":[0.9998682,0.00001405225,0.00003106155,0.0000140167,0.00005535625,0.0000173036],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005526146,0.000004032715,0.0002421373,0.0000295866,0.000003085251,0.00002441257,0.00002153143,0.00004847552,0.9980198,0.00008081824,0.00005682619,0.001414094],"study_design_scores_gemma":[0.000003613731,0.00007087881,0.001127171,0.000002735864,0.000005220306,0.00008146098,0.0000351474,0.0002661087,0.9961145,0.00003114149,0.002258088,0.000004062846],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.990485,0.0007609132,0.004217699,0.00009062816,0.00003093456,0.00002740637,0.0005234437,0.0001453061,0.003718647],"genre_scores_gemma":[0.9878372,0.0004680554,0.004691014,0.00005246943,0.000008244652,0.00002761348,0.0006791646,0.0000357603,0.006200537],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00162871,"threshold_uncertainty_score":0.005244434,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003960094741849418,"score_gpt":0.1916793409263261,"score_spread":0.1877192461844767,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}