{"id":"W2020983009","doi":"10.1021/om060390j","title":"Ortho-Selective C−H Activation of Substituted Benzenes Effected by a Tungsten Alkylidene Complex without Substituent Coordination","year":2006,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":36,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Selectivity; Substituent; Steric effects; Thermal decomposition; Medicinal chemistry; Chlorobenzene; Neopentane; Stereochemistry; Organic chemistry; Molecule; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002121028,0.0004287785,0.0007442352,0.0002588476,0.0001912023,0.0000778762,0.0003922354,0.0002060725,0.008063938],"category_scores_gemma":[0.0001621707,0.0004251547,0.0002483177,0.001258203,0.0001644301,0.0003112285,0.0000946961,0.0001828029,0.00003819885],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002453628,"about_ca_system_score_gemma":0.00008240331,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007219648,"about_ca_topic_score_gemma":0.0001721596,"domain_scores_codex":[0.9975704,0.00006264848,0.0007581406,0.0006024903,0.0005913296,0.0004149829],"domain_scores_gemma":[0.9981693,0.0001983722,0.000577394,0.0005771974,0.0003674546,0.0001103026],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006404029,0.0005191319,0.01278761,0.0001266087,0.0003429213,0.000001683071,0.00005009431,0.00006174597,0.9816471,0.00155726,0.0002354845,0.002606324],"study_design_scores_gemma":[0.001050786,0.00003261548,0.0516034,0.00004999679,0.0004252654,0.000008519529,0.00007779591,0.0005534103,0.9312676,0.0002422291,0.01414086,0.0005475716],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9835061,0.0002568598,0.001613889,0.0001434436,0.00003236212,0.0002301762,0.0001657535,0.0001949947,0.01385637],"genre_scores_gemma":[0.9944989,0.00002528241,0.0004907286,0.00001789241,0.00008915728,0.00005122403,0.002278047,0.00007932289,0.002469426],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05037954,"threshold_uncertainty_score":0.9998201,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009804362218393694,"score_gpt":0.2149329363473587,"score_spread":0.205128574128965,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}