{"id":"W2021010602","doi":"10.1002/chin.201349098","title":"ChemInform Abstract: A Ligand‐Free Palladium‐Catalyzed Cross‐Coupling of Aryl Sulfinates with Aryl Bromides.","year":2013,"lang":"en","type":"article","venue":"ChemInform","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Concordia University","funders":"","keywords":"Chemistry; Aryl; Palladium; Ligand (biochemistry); Catalysis; Coupling (piping); Combinatorial chemistry; Medicinal chemistry; Polymer chemistry; Organic chemistry; Biochemistry; Metallurgy; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002734543,0.000845299,0.0002195247,0.0007123564,0.0004036968,0.0004991728,0.0007019239,0.0005252711,0.0127525],"category_scores_gemma":[0.0001647709,0.0003739468,0.0002776696,0.000419968,0.0003033838,0.0003785903,0.0005297869,0.0009325765,0.005655179],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005940093,"about_ca_system_score_gemma":0.0009621924,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009469552,"about_ca_topic_score_gemma":0.002271531,"domain_scores_codex":[0.9997385,0.0000283892,0.00001248887,0.00005408455,0.0001244002,0.00004201409],"domain_scores_gemma":[0.9999355,0.000008035851,0.000013691,0.00001062839,0.0000147868,0.00001732755],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004482536,0.0001518223,0.000184963,0.0008604652,0.00007546274,0.0005127093,0.000155613,0.0008336674,0.9118203,0.007824958,0.01148674,0.06564505],"study_design_scores_gemma":[0.00008180275,0.0002464831,0.0004691208,0.00002790374,0.00004212563,0.0005649516,0.00002211101,0.000788976,0.9268442,0.0004198742,0.07046831,0.00002422678],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.3743256,0.01336584,0.2899938,0.00280875,0.001561366,0.001021278,0.01044992,0.01266544,0.293808],"genre_scores_gemma":[0.8321879,0.00873457,0.06821639,0.0007529774,0.0001762531,0.0002435173,0.006867785,0.0006147006,0.08220588],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0127525,"threshold_uncertainty_score":0.04266137,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01150215112871291,"score_gpt":0.2318432267499524,"score_spread":0.2203410756212394,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}