{"id":"W2021114871","doi":"10.6028/jres.107.015","title":"Water calorimetry: A correction to the heat defect calculations","year":2002,"lang":"en","type":"article","venue":"Journal of Research of the National Institute of Standards and Technology","topic":"Spectroscopy and Quantum Chemical Studies","field":"Physics and Astronomy","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada","funders":"","keywords":"Calorimetry; Water model; Thermodynamics; Consistency (knowledge bases); Aqueous solution; Materials science; Heat capacity; Physics; Analytical Chemistry (journal); Astrophysics; Chemistry; Physical chemistry; Mathematics; Geometry; Molecular dynamics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00081967,0.00005163866,0.0001461824,0.00022431,0.0002482424,0.00001054164,0.0002002819,0.00003229102,0.00006874162],"category_scores_gemma":[0.0003493259,0.00002424098,0.00008589833,0.0005118671,0.0004154983,0.00006723055,0.0001241682,0.0003406286,7.554787e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007357419,"about_ca_system_score_gemma":0.00006323009,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007181759,"about_ca_topic_score_gemma":0.00002049948,"domain_scores_codex":[0.9988821,0.00003099003,0.0002241825,0.00006503719,0.0006678792,0.0001298233],"domain_scores_gemma":[0.9984176,0.0000967939,0.00006488342,0.00007120669,0.001322384,0.00002714106],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"theoretical_or_conceptual","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005179111,0.0009675141,0.04752457,0.00009453459,0.001759179,0.000004437808,0.001458909,0.002592283,0.2385765,0.4743151,0.2043497,0.02783936],"study_design_scores_gemma":[0.001231716,0.0008295762,0.002474575,0.0002671416,0.00007040404,0.00004245111,0.000767709,0.0009690925,0.6404285,0.06411562,0.28866,0.0001431859],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9728428,0.0005838193,0.001403585,0.02074563,0.0004806358,0.0001710996,0.00009269072,0.000004617035,0.003675141],"genre_scores_gemma":[0.9995399,0.00003394609,0.0001454198,0.00001150702,0.0001304318,0.000003833175,4.804124e-7,0.000002639768,0.0001318646],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4101995,"threshold_uncertainty_score":0.1909305,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04513260035341156,"score_gpt":0.3773774390428942,"score_spread":0.3322448386894826,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}