{"id":"W2021179993","doi":"10.1021/es801759k","title":"Carbon and Chlorine Isotope Fractionation during Aerobic Oxidation and Reductive Dechlorination of Vinyl Chloride and <i>cis</i>-1,2-Dichloroethene","year":2008,"lang":"en","type":"article","venue":"Environmental Science & Technology","topic":"Environmental remediation with nanomaterials","field":"Engineering","cited_by":141,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung","keywords":"Chemistry; Chlorine; Isotopes of chlorine; Kinetic isotope effect; Isotope fractionation; Vinyl chloride; Reductive dechlorination; Isotopes of carbon; Isotope; Carbon fibers; Inorganic chemistry; Environmental chemistry; Fractionation; Organic chemistry; Total organic carbon; Biodegradation; Deuterium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001874053,0.0002787492,0.0002651552,0.0002331101,0.000198441,0.0003843906,0.0002445935,0.000269102,0.0003205314],"category_scores_gemma":[0.0003187848,0.0001564908,0.0002017819,0.000246936,0.0002939487,0.0002103924,0.000203218,0.0002881632,0.00008269154],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000634548,"about_ca_system_score_gemma":0.0003705798,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.008790187,"about_ca_topic_score_gemma":0.00966729,"domain_scores_codex":[0.9997621,0.00002498401,0.000009892207,0.00006613217,0.0000717834,0.00006510061],"domain_scores_gemma":[0.9998679,0.00003517902,0.00002744465,0.000008903135,0.00004505493,0.00001555608],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001019086,0.00000870434,0.001192786,0.00002464682,0.000005883712,0.00002315422,0.00004363408,0.000189034,0.9963892,0.00002476833,0.00001113876,0.001985197],"study_design_scores_gemma":[0.000003931166,0.0001296035,0.008421983,0.000002658685,0.000008423135,0.00003303557,0.0000542345,0.0008114948,0.9901837,0.0000238482,0.0003202429,0.00000699781],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9987127,0.0001700971,0.0006139671,0.00000905383,0.000002909773,0.00000661997,0.0001096009,0.000008252794,0.0003668038],"genre_scores_gemma":[0.9981103,0.0002364626,0.0006825826,0.00001315227,0.000001743677,0.000008623399,0.0001876239,0.00000922766,0.00075023],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008790187,"threshold_uncertainty_score":0.01747805,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00456594242500854,"score_gpt":0.1834142466603456,"score_spread":0.1788483042353371,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}