{"id":"W2021259596","doi":"10.1016/j.jorganchem.2013.07.076","title":"Formation of phosphorus heterocycles using a cationic electrophilic phosphinidene complex","year":2013,"lang":"en","type":"article","venue":"Journal of Organometallic Chemistry","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Regina","funders":"","keywords":"Phosphinidene; Chemistry; Cationic polymerization; Electrophile; Phosphorus; Organic chemistry; Photochemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001903661,0.0003732652,0.0002275616,0.0002725456,0.0003572817,0.0003997215,0.0005167599,0.0005414736,0.003012501],"category_scores_gemma":[0.0002227835,0.0002053117,0.00019588,0.0001727513,0.0002148183,0.000386349,0.0005527104,0.0004189027,0.0005472988],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003283917,"about_ca_system_score_gemma":0.0002583673,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002597465,"about_ca_topic_score_gemma":0.000403968,"domain_scores_codex":[0.9998491,0.00001856763,0.00001047143,0.00004127634,0.00003159502,0.0000489596],"domain_scores_gemma":[0.9999346,0.00001485952,0.00001493179,0.00001093606,0.000006222358,0.00001851611],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004514438,0.0001662614,0.0002721229,0.0003581887,0.00003773284,0.0009044902,0.0002631464,0.001264367,0.9710509,0.0107443,0.001120882,0.01336614],"study_design_scores_gemma":[0.000100905,0.0005975568,0.0003679387,0.000009965004,0.00001639583,0.0003151192,0.00002829319,0.001156185,0.9899936,0.0004707496,0.006924469,0.00001884764],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9650568,0.0009446681,0.008688924,0.0002373225,0.000125472,0.0001219767,0.0002655945,0.0002866358,0.02427254],"genre_scores_gemma":[0.9941095,0.0003447752,0.001754456,0.0000411624,0.00001104521,0.0000420552,0.0001260997,0.00002401243,0.003546924],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003012501,"threshold_uncertainty_score":0.01007783,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01982167773099701,"score_gpt":0.2274442471230787,"score_spread":0.2076225693920817,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}