{"id":"W2021304100","doi":"10.1021/ie101218k","title":"Water Solubility in Supercritical Methane, Nitrogen, and Carbon Dioxide: Measurement and Modeling from 422 to 483 K and Pressures from 3.6 to 134 MPa","year":2011,"lang":"en","type":"article","venue":"Industrial & Engineering Chemistry Research","topic":"Phase Equilibria and Thermodynamics","field":"Engineering","cited_by":85,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"University of Calgary","keywords":"Fugacity; Supercritical fluid; Methane; Chemistry; Solubility; Equation of state; Carbon dioxide; Thermodynamics; Nitrogen; Supercritical carbon dioxide; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0008890381,0.0002544972,0.000344844,0.00010614,0.00003286023,0.00006448054,0.0002392753,0.0002960616,0.00003028774],"category_scores_gemma":[0.0005300808,0.000249763,0.0000240914,0.0001495077,0.00004662286,0.00009806758,0.0003740049,0.0007616929,0.00000140363],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001587251,"about_ca_system_score_gemma":0.00003271586,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00250105,"about_ca_topic_score_gemma":0.00006024384,"domain_scores_codex":[0.9980422,0.00005183604,0.0003120884,0.0004875457,0.0004750646,0.0006313009],"domain_scores_gemma":[0.9989102,0.0001356151,0.000002956491,0.00038727,0.00008033905,0.0004835979],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001136408,0.00002516436,0.001539432,0.00005887444,0.00006925746,0.00002400984,0.0007498795,0.005622684,0.9915079,0.00000431326,0.000006863767,0.0002779965],"study_design_scores_gemma":[0.000700216,0.00002770144,0.0002587124,0.0001344055,0.0000195852,0.000002822866,0.00009464651,0.2005206,0.7974623,0.0004698645,0.00003828434,0.0002708409],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.998509,0.0005341612,0.0001237006,0.0000661238,0.00009707211,0.0003158908,0.00005918787,0.00009798617,0.0001968958],"genre_scores_gemma":[0.9994099,0.00001998544,0.0001597182,0.000003592027,0.0002732937,0.00006503031,0.00001252285,0.00005235595,0.000003619844],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1948979,"threshold_uncertainty_score":0.9999955,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.1594903348311893,"score_gpt":0.2967068566816149,"score_spread":0.1372165218504256,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}