{"id":"W2021315617","doi":"10.1021/om0009482","title":"Associative Stereomutation of a Pentacoordinate Transition-Metal Complex:  Access to the Required Octahedral Intermediate through Stereoselective CO Uptake at an Unsaturated Ruthenium(II) Center","year":2001,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":35,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"","keywords":"Chemistry; Diastereomer; Stereoselectivity; Ruthenium; Yield (engineering); Toluene; Octahedron; Medicinal chemistry; Center (category theory); Metal; Transition metal; Stereochemistry; Chloride; Catalysis; Crystallography; Organic chemistry; Crystal structure","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003429842,0.000543329,0.0008509475,0.000196326,0.0005540043,0.0002188034,0.001159293,0.000185683,0.02224349],"category_scores_gemma":[0.0001156964,0.0004393838,0.0004007357,0.001356468,0.0002175436,0.00104831,0.0003635142,0.0002920855,0.0001202702],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004949741,"about_ca_system_score_gemma":0.00008116903,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001446877,"about_ca_topic_score_gemma":0.0007119644,"domain_scores_codex":[0.9967124,0.0002000683,0.0009505384,0.0007931042,0.0006892721,0.0006545868],"domain_scores_gemma":[0.9977975,0.0001753836,0.0006254999,0.0008075371,0.000379961,0.0002140936],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001937962,0.003222097,0.008146618,0.0002165627,0.004154872,0.00006066841,0.06154914,0.0001507063,0.88936,0.0005305391,0.0009004305,0.02977043],"study_design_scores_gemma":[0.01150839,0.001854099,0.2587446,0.000391545,0.003590877,0.0003199961,0.02527928,0.004027467,0.5259804,0.00227674,0.1609971,0.005029526],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9890294,0.00005451929,0.0007251265,0.001115281,0.0001300721,0.0004300059,0.001023426,0.0001234172,0.007368742],"genre_scores_gemma":[0.9945962,0.00006106345,0.0001929994,0.0004723285,0.0002103149,0.00006714082,0.001719926,0.0001011512,0.00257888],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3633795,"threshold_uncertainty_score":0.9998058,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04403721977514218,"score_gpt":0.3021165354872747,"score_spread":0.2580793157121325,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}