{"id":"W2021344553","doi":"10.1002/marc.200400531","title":"Nitroxide‐Mediated Polymerization of Styrene in a Continuous Tubular Reactor","year":2005,"lang":"en","type":"article","venue":"Macromolecular Rapid Communications","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":63,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University; Xerox (Canada)","funders":"","keywords":"Polymerization; Nitroxide mediated radical polymerization; Styrene; Polymer chemistry; Molar mass distribution; Materials science; Kinetics; Chemical engineering; Batch reactor; Living polymerization; Radical polymerization; Chemistry; Polymer; Copolymer; Organic chemistry; Composite material; Catalysis; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000107743,0.0001734018,0.0002822826,0.0001360265,0.00007156689,0.00002168864,0.0006756692,0.0001190821,0.0005089135],"category_scores_gemma":[0.0001280977,0.000198441,0.00008781247,0.0003491632,0.0001244697,0.0001607406,0.0001698341,0.0001913718,0.00002120823],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005848465,"about_ca_system_score_gemma":0.00004831032,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007049629,"about_ca_topic_score_gemma":0.00003664781,"domain_scores_codex":[0.9987072,0.0001000219,0.0005706206,0.0002171867,0.0001790057,0.000226019],"domain_scores_gemma":[0.9978973,0.0001247892,0.0003033152,0.001539226,0.00008100287,0.00005436318],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001752263,0.0002957141,0.000888126,0.0000181945,0.00003033655,0.000001849988,0.0002988246,0.000007930003,0.9634153,0.0007328316,0.000007888044,0.03428555],"study_design_scores_gemma":[0.0006459298,0.00001574847,0.000772923,0.00009293968,0.00003081655,0.00000661233,0.0001526074,0.001984888,0.9724878,0.00005927466,0.02351137,0.000239075],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9677955,0.009862695,0.005761195,0.002149142,0.00004105947,0.0002492196,0.000196134,0.0001903125,0.01375472],"genre_scores_gemma":[0.9951326,0.001009099,0.002684759,0.000126761,0.00002817246,0.0000708531,0.0007858811,0.00004121608,0.0001206476],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03404647,"threshold_uncertainty_score":0.8092189,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01033058725460025,"score_gpt":0.2382827929195293,"score_spread":0.227952205664929,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}