{"id":"W2021467562","doi":"10.1139/v04-158","title":"Synthesis and thermolysis of a spiro-fused oxadiazoline Evidence for sequential formation of carbene and oxirane intermediates, and for oxirane dimerization","year":2004,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Reactions and Mechanisms","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Dimer; Carbene; Thermal decomposition; Octane; Benzene; Water dimer; Decomposition; Cyclopropane; Photochemistry; Polymer chemistry; Catalysis; Medicinal chemistry; Organic chemistry; Ring (chemistry); Molecule; Hydrogen bond","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008207907,0.0001336282,0.0000983418,0.00007511665,0.00007422296,0.0001324295,0.0001475682,0.0001737904,0.001090732],"category_scores_gemma":[0.00009374188,0.00008387998,0.0001107433,0.00007577335,0.0001038888,0.0001366958,0.00008080735,0.0002777888,0.0002388742],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000150044,"about_ca_system_score_gemma":0.0001101825,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003235037,"about_ca_topic_score_gemma":0.0005230997,"domain_scores_codex":[0.9999416,0.000004391685,0.000003712388,0.00002056217,0.00001641498,0.00001330284],"domain_scores_gemma":[0.9999431,0.000008553565,0.00001912133,0.000008978724,0.000007239612,0.00001303446],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001685621,0.00000506336,0.0000554268,0.000009400032,0.000001172847,0.00003160863,0.00001174314,0.0000362252,0.9994968,0.00003128167,0.000006217042,0.0002982031],"study_design_scores_gemma":[0.000007852201,0.0001624184,0.002058955,0.000002262728,0.000005133991,0.000158545,0.00001128619,0.0004120334,0.9962347,0.00002532332,0.0009183083,0.000003128386],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9953094,0.000463935,0.002384238,0.00002874635,0.000008197609,0.00001454298,0.000152094,0.00002927072,0.001609477],"genre_scores_gemma":[0.9963762,0.0001979575,0.001663845,0.00001066835,0.000001859073,0.00000681143,0.000170146,0.000008880297,0.001563432],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001090732,"threshold_uncertainty_score":0.003648877,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02649156053294364,"score_gpt":0.2539916843164496,"score_spread":0.227500123783506,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}